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kozerog [31]
3 years ago
8

What is the pH of a solution that contains 0.83M HCN (Ka = 4.9x10-10) and 0.64 M potassium cyanide?

Chemistry
1 answer:
oksian1 [2.3K]3 years ago
5 0

Answer:

pH= 9.2

Explanation:

Henderson hasselbach equation

pKa= log Ka= log (4.9 x 10^-10)=9.3

pH=Pka+log \frac{[A-]}{[HA]}

pH=9.3+log \frac{[CN-]}{[HCN]}

pH=9.3+log \frac{[0.64 M]}{[0.83 M]}

pH= 9.2

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A solution made by dissolving 33 mg of insulin in 6.5 mL of water has an osmotic pressure of 15.5 mmHg at 25°C. Calculate the mo
Liula [17]

<u>Answer:</u> The molar mass of the insulin is 6087.2 g/mol

<u>Explanation:</u>

To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

\pi=iMRT

Or,

\pi=i\times \frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}\times RT

where,

\pi = osmotic pressure of the solution = 15.5 mmHg

i = Van't hoff factor = 1 (for non-electrolytes)

Mass of solute (insulin) = 33 mg = 0.033 g   (Conversion factor: 1 g = 1000 mg)

Volume of solution = 6.5 mL

R = Gas constant = 62.364\text{ L.mmHg }mol^{-1}K^{-1}

T = temperature of the solution = 25^oC=[273+25]=298K

Putting values in above equation, we get:

15.5mmHg=1\times \frac{0.033\times 1000}{\text{Molar mass of insulin}\times 6.5}\times 62.364\text{ L.mmHg }mol^{-1}K^{-1}\times 298K\\\\\text{molar mass of insulin}=\frac{1\times 0.033\times 1000\times 62.364\times 298}{15.5\times 6.5}=6087.2g/mol

Hence, the molar mass of the insulin is 6087.2 g/mol

8 0
3 years ago
Assume that you have a cylinder with a movable piston. What would happen to the gas pressure inside the cylinder if you do the f
pishuonlain [190]

Answer:

A. The pressure will increase 4 times. P₂ = 4 P₁

B. The pressure will decrease to half its value. P₂ = 0.5 P₁

C. The pressure will decrease to half its value. P₂ = 0.5 P₁

Explanation:

Initially, we have n₁ moles of a gas that occupy a volume V₁ at temperature T₁ and pressure P₁.

<em>What would happen to the gas pressure inside the cylinder if you do the following?</em>

<em />

<em>Part A: Decrease the volume to one-fourth the original volume while holding the temperature constant. Express your answer in terms of the variable P initial.</em>

V₂ = 0.25 V₁. According to Boyle's law,

P₁ . V₁ = P₂ . V₂

P₁ . V₁ = P₂ . 0.25 V₁

P₁ = P₂ . 0.25

P₂ = 4 P₁

<em>Part B: Reduce the Kelvin temperature to half its original value while holding the volume constant. Express your answer in terms of the variable P initial.</em>

T₂ = 0.5 T₁. According to Gay-Lussac's law,

\frac{P_{1}}{T_{1}} =\frac{P_{2}}{T_{2}}\\\frac{P_{1}}{T_{1}} =\frac{P_{2}}{0.5T_{1}}\\\\P_{2}=0.5P_{1}

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n₂ = 0.5 n₁.

P₁ in terms of the ideal gas equation is:

P_{1}=\frac{n_{1}.R.T_{1}}{V_{1}}

P₂ in terms of the ideal gas equation is:

P_{2}=\frac{n_{2}.R.T_{1}}{V_{1}}=\frac{0.5n_{1}.R.T_{1}}{V_{1}}=0.5P_{1}

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Answer:

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Explanation:

These elements are rare because:

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1 ) your favorite recipe for preparing 100 brownies requires the following : 6 eggs , 5 cups flour and 2 sticks of butter . how
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<em />If 100 brownies require 6 eggs, 5 cups of flour, and 2 sticks of butter. Then, 50 brownies should require half of those required to make 100 brownies. Use ratio and proportion to determine the number of eggs needed:

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