Given that the density of the unknown substance is 0.79 g/cm3 and is soluble in water, the possible substances it could be are;
i) t-butanol
ii) ethanol
iii) 2-propanol
iv) acetone
However, the actual identity of the unknown substance can be obtained by carrying out a boiling point test. The four substances listed above have different boiling points. Hence the boiling point of the unknown substance ultimately discloses its identity.