Answer:
Kb = 6.22x10⁻⁷
Explanation:
Triethanolamine, C₆H₁₅O₃N, is in equilibrium with water:
C₆H₁₅O₃N(aq) + H₂O(l) ⇄ C₆H₁₅O₃NH⁺(aq) + OH⁻(aq)
Kb is defined from concentrations in equilibrium, thus:
Kb = [C₆H₁₅O₃NH⁺] [OH⁻] / [C₆H₁₅O₃N]
The equilibrium concentration of these compounds could be written as:
[C₆H₁₅O₃N] = 0.486M - X
[C₆H₁₅O₃NH⁺] = X
[OH⁻] = X
pH is -log [H⁺], thus, [H⁺] = 10^-pH = 1.820x10⁻¹¹M
Also, Kw = [OH⁻] ₓ [H⁺];
1x10⁻¹⁴ = [OH⁻] ₓ [H⁺]
1x10⁻¹⁴ = [OH⁻] ₓ [1.820x10⁻¹¹M]
5.495x10⁻⁴M = [OH⁻], that means <em>X = 5.495x10⁻⁴M</em>
Replacing in Kb formula:
Kb = [5.495x10⁻⁴M] [5.495x10⁻⁴M] / [0.486M-5.495x10⁻⁴M]
<em>Kb = 6.22x10⁻⁷</em>
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Scientists often repeat one or more steps several times.
All acids only conduct electric current when they are dissolved in water, because when they are in an aqueous medium, they undergo ionization, i.e. release <span>ions.</span><span>
HCl --> H</span>⁺ + Cl⁻
The bases also conduct electric current in solution, because the Ionic dissociation sufferers (release the existing ions in the formula) and molecular ionization, suffer the reacting with water and releasing ions.
NaOH ---> Na⁺ + OH⁻
hope this helps!
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