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2 years ago

Consider the molecules H2O, H2S, H2Se, and H2Te. Which do you expect to have the highest boiling point, and why?

Chemistry

1 answer:

STatiana [176]2 years ago

5 0

Answer:

a. H20,because it experiences hydrogen bonding.

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A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would

Olenka [21]

Answer:

C. $Ca_3(PO_4)_2$ will precipitate out first

the percentage of $Ca^{2+}$ remaining = 12.86%

Explanation:

Given that:

A solution contains:

$[Ca^{2+}] = 0.0440 \ M$

$[Ag^+] = 0.0940 \ M$

From the list of options , Let find the dissociation of $Ag_3PO_4$

$Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}$

where;

Solubility product constant Ksp of $Ag_3PO_4$ is $8.89 \times 10^{-17}$

Thus;

$Ksp = [Ag^+]^3[PO_4^{3-}]$

replacing the known values in order to determine the unknown ; we have :

$8.89 \times 10 ^{-17} = (0.0940)^3[PO_4^{3-}]$

$\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3} = [PO_4^{3-}]$

$[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}$

$[PO_4^{3-}] =1.07 \times 10^{-13}$

The dissociation of $Ca_3(PO_4)_2$

The solubility product constant of $Ca_3(PO_4)_2$ is $2.07 \times 10^{-32}$

The dissociation of $Ca_3(PO_4)_2$ is :

$Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}$

Thus;

$Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2$

$2.07 \times 10^{-33} = (0.0440)^3 [PO_4^{3-}]^2$

$\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}= [PO_4^{3-}]^2$

$[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}$

$[PO_4^{3-}]^2 = 2.43 \times 10^{-29}$

$[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}$

$[PO_4^{3-}] =4.93 \times 10^{-15}$

Thus; the phosphate anion needed for precipitation is smaller i.e $4.93 \times 10^{-15}$ in $Ca_3(PO_4)_2$ than in $Ag_3PO_4$ $1.07 \times 10^{-13}$

Therefore:

$Ca_3(PO_4)_2$ will precipitate out first

To determine the concentration of $[Ca^+]$ when the second cation starts to precipitate ; we have :

$Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2$

$2.07 \times 10^{-33} = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2$

$[Ca^{2+}]^3 = \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}$

$[Ca^{2+}]^3 =1.808 \times 10^{-7}$

$[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}$

$[Ca^{2+}] =0.00566$

This implies that when the second cation starts to precipitate ; the concentration of $[Ca^{2+}]$ in the solution is 0.00566

Therefore;

the percentage of $Ca^{2+}$ remaining = concentration remaining/initial concentration × 100%

the percentage of $Ca^{2+}$ remaining = 0.00566/0.0440 × 100%

the percentage of $Ca^{2+}$ remaining = 0.1286 × 100%

the percentage of $Ca^{2+}$ remaining = 12.86%

5 0

3 years ago

Which evidence supports the claim that matter can bend light waves?

solmaris [256]

Answer:d

Explanation:I’m not 100% sure how to explain it but I’m almost for sure it’s d.

8 0

2 years ago

Read 2 more answers

Any element can always be identified by its:

Alborosie

Explanation:

atomic mass

Really...i think it can also be atomic number..

3 0

3 years ago

The boiling point of a substance in City A is found to be 145°C the boiling point of th same substance in Xity B is 141°C which

DochEvi [55]

City B. Higher altitudes have lower boiling points due to lower atmospheric pressure at higher altitudes

4 0

3 years ago

Any help would be appreciated. Confused.

masya89 [10]

Answer:

q(problem 1) = 25,050 joules; q(problem 2) = 4.52 x 10⁶ joules

Explanation:

To understand these type problems one needs to go through a simple set of calculations relating to the 'HEATING CURVE OF WATER'. That is, consider the following problem ...

=> Calculate the total amount of heat needed to convert 10g ice at -10°C to steam at 110°C. Given are the following constants:

Heat of fusion (ΔHₓ) = 80 cal/gram

Heat of vaporization (ΔHv) = 540 cal/gram

specific heat of ice [c(i)] = 0.50 cal/gram·°C

specific heat of water [c(w)] = 1.00 cal/gram·°C

specific heat of steam [c(s)] = 0.48 cal/gram·°C

Now, the problem calculates the heat flow in each of five (5) phase transition regions based on the heating curve of water (see attached graph below this post) ... Note two types of regions (1) regions of increasing slopes use q = mcΔT and (2) regions of zero slopes use q = m·ΔH.

q(warming ice) = m·c(i)·ΔT = (10g)(0.50 cal/g°C)(10°C) = 50 cal

q(melting) = m·ΔHₓ = (10g)(80cal/g) 800 cal

q(warming water) = m·c(w)·ΔT = (10g)(1.00 cal/g°C)(100°C) = 1000 cal

q(evaporation of water) = m·ΔHv = (10g)(540cal/g) = 5400 cal

q(heating steam) = m·c(s)·ΔT = (10g)(0.48 cal/g°C)(10°C) = 48 cal

Q(total) = ∑q = (50 + 800 + 1000 + 5400 + 48) = 7298 cals. => to convert to joules, multiply by 4.184 j/cal => q = 7298 cals x 4.184 j/cal = 30,534 joules = 30.5 Kj.

Now, for the problems in your post ... they represent fragments of the above problem. All you need to do is decide if the problem contains a temperature change (use q = m·c·ΔT) or does NOT contain a temperature change (use q = m·ΔH).

Problem 1: Given Heat of Fusion of Water = 334 j/g, determine heat needed to melt 75g ice.

Since this is a phase transition (melting), NO temperature change occurs; use q = m·ΔHₓ = (75g)(334 j/g) = 25,050 joules.

Problem 2: Given Heat of Vaporization = 2260 j/g; determine the amount of heat needed to boil to vapor 2 Liters water ( = 2000 grams water ).

Since this is a phase transition (boiling = evaporation), NO temperature change occurs; use q = m·ΔHf = (2000g)(2260 j/g) = 4,520,000 joules = 4.52 x 10⁶ joules.

Problems containing a temperature change:

NOTE: A specific temperature change will be evident in the context of problems containing temperature change => use q = m·c·ΔT. Such is associated with the increasing slope regions of the heating curve. Good luck on your efforts. Doc :-)

5 0

3 years ago