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Evgen [1.6K]
3 years ago
9

Converting the following mm Hg (torr) to standard

Chemistry
1 answer:
11Alexandr11 [23.1K]3 years ago
5 0

Explanation:

Given:

20.5 torr

78.6 torr

225 torr

Change into atm

Computation:

We know that;

1 torr = 0.00131579 atm

So,

1. 20.5 torr

= 20.5 x 0.00131579 atm

= 0.02697

= 0.027 atm (Approx)

2. 78.6 torr

= 78.6 x 0.00131579 atm

= 0.103090

= 0.103 atm (Approx)

3. 225 torr

= 225 x 0.00131579 atm

= 0.2960

= 0.296 atm (Approx)

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Answer:

I will work only one of the listed equations ... you follow the given example for the remaining reactions. Thank you :-)

Rxn 1: Pt°(s) + Fe⁺²(aq) ⇄ Pt⁺²(aq) + Fe°(s)

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Explanation:

Pt°(s) + Fe⁺²(aq) ⇄ Pt⁺²(aq) + Fe°(s) ⇔

Pt°(s)|Pt⁺²[0.057M]║Fe⁺²[0.006M]|Fe°(s)

As written, Pt° is shown undergoing oxidation with Fe⁺² undergoing reduction. Applying the reduction potentials to the analytical equations for E(cell) and ΔG(cell) gives E(Pt/Fe⁺²) < 0 and ΔG(Pt/Fe⁺²) > 0 which indicate a non-spontaneous process. The following supports this conclusion.

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E°(Pt/Fe⁺²) =E°(Redn) - E°(Oxidn) =E°(Fe⁺²) - E°(Pt⁺²)

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n = electrons transferred = 2

E(nonstd) = E°(std) - (0.0592/n)logQ);

Q = [Pt⁺²]/[Fe⁺²]

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Also, if ΔG(cell) > 0 => indicates non-spontaneous process

ΔG(Pt/Fe⁺²) = - nFE = -(2)(96,500Coulombs)((-1.664v) > 0 Kj => nonspontaneous rxn. (1 Coulomb-volt = 1 Kilojoule)

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