Answer:
E = 1.602v
Explanation:
Use the Nernst Equation => E(non-std) = E⁰(std) – (0.0592/n)logQc …
Zn⁰(s) => Zn⁺²(aq) + 2 eˉ
2Ag⁺(aq) + 2eˉ=> 2Ag⁰(s)
_____________________________
Zn⁰(s) + 2Ag⁺(aq) => Zn⁺²(aq) + 2Ag(s)
Given E⁰ = 1.562v
Qc = [Zn⁺²(aq)]/[Ag⁺]² = (1 x 10ˉ³)/(0.150)² = 0.044
E = E⁰ -(0.0592/n)logQc = 1.562v – (0.0592/2)log(0.044) = 1.602v
The volume of the 0.279 M Ca(OH)₂ solution required to neutralize 24.5 mL of 0.390 M H₃PO₄ is 51.4 mL
<h3>Balanced equation </h3>
2H₃PO₄ + 3Ca(OH)₂ —> Ca₃(PO₄)₂ + 6H₂O
From the balanced equation above,
- The mole ratio of the acid, H₃PO₄ (nA) = 2
- The mole ratio of the base, Ca(OH)₂ (nB) = 3
<h3>How to determine the volume of Ca(OH)₂ </h3>
- Molarity of acid, H₃PO₄ (Ma) = 0.390 M
- Volume of acid, H₃PO₄ (Va) = 24.5 mL
- Molarity of base, Ca(OH)₂ (Mb) = 0.279 M
- Volume of base, Ca(OH)₂ (Vb) =?
MaVa / MbVb = nA / nB
(0.39 × 24.5) / (0.279 × Vb) = 2/3
9.555 / (0.279 × Vb) = 2/3
Cross multiply
2 × 0.279 × Vb = 9.555 × 3
0.558 × Vb = 28.665
Divide both side by 0.558
Vb = 28.665 / 0.558
Vb = 51.4 mL
Thus, the volume of the Ca(OH)₂ solution needed is 51.4 mL
Learn more about titration:
brainly.com/question/14356286
Answer: 4.21×10⁻⁸
Explanation:
1) Assume a general equation for the ionization of the weak acid:
Let HA be the weak acid, then the ionization equation is:
HA ⇄ H⁺ + A⁻
2) Then, the expression for the ionization constant is:
Ka = [H⁺][A⁻] / [HA]
There, [H⁺] = [A⁻], and [HA] = 0.150 M (data given)
3) So, you need to determine [H⁺] which you do from the pH.
By definition, pH = - log [H⁺]
And from the data given pH = 4.1
⇒ 4.10 = - log [H⁺] ⇒ [H⁺] = antilog (- 4.10) = 7.94×10⁻⁵
4) Now you have all the values to calculate the expression for Ka:
ka = 7.94×10⁻⁵ × 7.94×10⁻⁵ / 0.150 = 4.21×10⁻⁸