(a)
pH = 4.77
; (b)
[
H
3
O
+
]
=
1.00
×
10
-4
l
mol/dm
3
; (c)
[
A
-
]
=
0.16 mol⋅dm
-3
Explanation:
(a) pH of aspirin solution
Let's write the chemical equation as
m
m
m
m
m
m
m
m
l
HA
m
+
m
H
2
O
⇌
H
3
O
+
m
+
m
l
A
-
I/mol⋅dm
-3
:
m
m
0.05
m
m
m
m
m
m
m
m
l
0
m
m
m
m
m
l
l
0
C/mol⋅dm
-3
:
m
m
l
-
x
m
m
m
m
m
m
m
m
+
x
m
l
m
m
m
l
+
x
E/mol⋅dm
-3
:
m
0.05 -
l
x
m
m
m
m
m
m
m
l
x
m
m
x
m
m
m
x
K
a
=
[
H
3
O
+
]
[
A
-
]
[
HA
]
=
x
2
0.05 -
l
x
=
3.27
×
10
-4
Check for negligibility
0.05
3.27
×
10
-4
=
153
<
400
∴
x
is not less than 5 % of the initial concentration of
[
HA
]
.
We cannot ignore it in comparison with 0.05, so we must solve a quadratic.
Then
x
2
0.05
−
x
=
3.27
×
10
-4
x
2
=
3.27
×
10
-4
(
0.05
−
x
)
=
1.635
×
10
-5
−
3.27
×
10
-4
x
x
2
+
3.27
×
10
-4
x
−
1.635
×
10
-5
=
0
x
=
1.68
×
10
-5
[
H
3
O
+
]
=
x
l
mol/L
=
1.68
×
10
-5
l
mol/L
pH
=
-log
[
H
3
O
+
]
=
-log
(
1.68
×
10
-5
)
=
4.77
(b)
[
H
3
O
+
]
at pH 4
[
H
3
O
+
]
=
10
-pH
l
mol/L
=
1.00
×
10
-4
l
mol/L
(c) Concentration of
A
-
in the buffer
We can now use the Henderson-Hasselbalch equation to calculate the
[
A
-
]
.
pH
=
p
K
a
+
log
(
[
A
-
]
[
HA
]
)
4.00
=
−
log
(
3.27
×
10
-4
)
+
log
(
[
A
-
]
0.05
)
=
3.49
+
log
(
[
A
-
]
0.05
)
log
(
[
A
-
]
0.05
)
=
4.00 - 3.49
=
0.51
[
A
-
]
0.05
=
10
0.51
=
3.24
[
A
-
]
=
0.05
×
3.24
=
0.16
The concentration of
A
-
in the buffer is 0.16 mol/L.
hope this helps :)
Answer:
probably
Explanation:
Because fossil fuel is the main fuel source, so any fuels that are not fossil fuels are alternative.
Answer:
If you have ever been in a room when a piping hot pizza was delivered, you have been made aware of the fact that gaseous molecules can quickly spread throughout a room, as evidenced by the pleasant aroma that soon reaches your nose. Although gaseous molecules travel at tremendous speeds (hundreds of meters per second), they collide with other gaseous molecules and travel in many different directions before reaching the desired target.
Explanation:
hope this helps
