Answer:
Explanation:
The formula of the reaction:
KClO₂ → KCl + O₂
To assign oxidation numbers, we have to obey some rules:
- Elements in an uncombined state or one whose atoms combine with one another to form molecules have an oxidation number of zero.
- The charge on simple ions signifies their oxidation number.
- The algebraic sum of all the oxidation number of all atoms in a neutral compound is zero. For radicals with charges, their oxidation number is the charge.
The oxidation number of K in KClO₂:
K + (-1) + 2(-2) = 0
K-5 = 0
K = +5
The oxidation number of K in KCl:
K + (-1) = 0
K = +1
The oxidation number Cl in KClO₂ is -1
For Cl in KCl, the oxidation number is -1
For O in KClO₂, the oxidation number is (2 x -2) = -4
For O in O₂, the oxidation number is 0
K moves from an oxidation state of +5 to +1. This is a gain of electrons and K has undergone reduction. We then say K is reduced.
O moves from an oxidation state of -4 to 0. This is a loss of electrons and O has undergone oxidation. We say O is oxidized.
Answer:
is the oxidizing agent
Explanation:
An oxidizing agent is an element in a reaction that accepts the electrons of another element. It is typically hydrogen, oxide, or any halogen. In this case, it is oxygen. The answer is 02.
Formic acid is the simplest carboxylic acid with a structure of HCOOH and has a pka of 3.75. The pka refers to the acidity of the molecule, which in this example refers to the molecules ability to give up the proton of the O-H. A decrease in the pka value corresponds to an increase in acidity, or an increase in the ability to give up a proton. When an acid gives up a proton, the remaining anionic species (in this case HCOO-) is called the conjugate base, and an increase in the stability of the conjugate base corresponds to an increase in acidity.
The pka of a carboxylic can be affected greatly by the presence of various functional groups within its structure. An example of an inductive effect changing the pka can be shown with trichloroacetic acid, Cl3CCOOH. This molecule has a pka of 0.7. The decrease in pka relative to formic acid is due to the presence of the Cl3C- group, and more specifically the presence of the chlorine atoms. The electronegative chlorine atoms are able to withdraw the electron density away from the oxygen atoms and towards themselves, thus helping to stabilize the negative charge and stabilize the conjugate base. This results in an increase in acidity and decrease in pka.
The same Cl3CCOOH example can be used to explain how dipoles can effect the acidity of carboxylic acids. Compared to standard acetic acid, H3CCOOH with a pka of 4.76, trichloroacetic acid is much more acidic. The difference between these structures is the presence of C-Cl bonds in place of C-H bonds. A C-Cl bond is much more polar than a C-H bond, due the large electronegativity of the chlorine atom. This results in a carbon with a partial positive charge and a chlorine with a partial negative charge. In the conjugate base of the acid, where the molecule has a negative charge localized on the oxygen atoms, the dipole moment of the C-Cl bond is oriented such that the partial positive charge is on the carbon that is adjacent to the oxygen atoms containing the negative charge. Therefore, the electrostatic attraction between the positive end of the C-Cl dipole and the negative charge of the anionic oxygen helps to stabilize the entire species. This level of stabilization is not present in acetic acid where there are C-H bonds instead of C-Cl bonds since the C-H bonds do not have a large dipole moment.
To understand how resonance can affect the pka of a species, we can simply compare the pka of a simple alcohol such as methanol, CH3OH, and formic acid, HCOOH. The pka of methanol is 16, suggesting that is is a very weak acid. Once methanol gives up that proton to become the conjugate base CH3O-, the charge cannot be stabilized in any way and is simply localized on the oxygen atom. However, with a carboxylic acid, the conjugate base, HCOO-, can stabilize the negative charge. The lone pair electrons containing the charge on the oxygen atom are able to migrate to the other oxygen atom of the carboxylic acid. The negative charge can now be shared between the two electronegative oxygen atoms, thus stabilizing the charge and decreasing the pka.
The molarity of the solution will be 0.72 m.
The majority of reactions take place in solutions, making it crucial to comprehend how the substance's concentration is expressed in a solution when it is present. The number of chemicals in a solution can be stated in a variety of ways, including.
The symbol for it is M, and it serves as one of the most often used concentration units. Its definition states how many moles of solute there are in a liter of solution.
Given data:
Molarity can be determined by the formula:
where, M is molarity and V is volume.
Put the value of given data in above equation.
57.3 × 0.497 m = M × 39.5 L
M = 0.72 m
Therefore, the molarity of the solution will be 0.72 m
To know more about molarity
brainly.com/question/18648803
#SPJ4
Explanation:
Fusion vs Fission
In fission, energy is gained by splitting apart heavy atoms, for example uranium, into smaller atoms such as iodine, caesium, strontium, xenon and barium, to name just a few. However, fusion is combining light atoms, for example two hydrogen isotopes, deuterium and tritium, to form the heavier helium. Both reactions release energy which, in a power plant, would be used to boil water to drive a steam generator, thus producing electricity.
