Explanation:
P1V1 = nRT1
P2V2 = nRT2
Divide one by the other:
P1V1/P2V2 = nRT1/nRT2
From which:
P1V1/P2V2 = T1/T2
(Or P1V1 = P2V2 under isothermal conditions)
Inverting and isolating T2 (final temp)
(P2V2/P1V1)T1 = T2 (Temp in K).
Now P1/P2 = 1
V1/V2 = 1/2
T1 = 273 K, the initial temp.
Therefore, inserting these values into above:
2 x 273 K = T2 = 546 K, or 273 C.
Thus, increasing the temperature to 273 C from 0C doubles its volume, assuming ideal gas behaviour. This result could have been inferred from the fact that the the volume vs temperature line above the boiling temperature of the gas would theoretically have passed through the origin (0 K) which means that a doubling of temperature at any temperature above the bp of the gas, doubles the volume.
From the ideal gas equation:
V = nRT/P or at constant pressure:
V = kT where the constant k = nR/P. Therefore, theoretically, at 0 K the volume is zero. Of course, in practice that would not happen since a very small percentage of the volume would be taken up by the solidified gas.
Answer:
146 kJ
Explanation:
There are two heat flows in this question.
Heat lost on cooling + heat lost on solidifying = 0
q₁ + q₂ = 0
mCΔT + nΔHsol = 0
Data:
m = 575 g
C = 0.449 J·K⁻¹g⁻¹
T_i = 1825 K
T_f = 1811 K
ΔHsol = -13.8 kJ·mol⁻¹
Calculations:
(a) Heat lost on cooling
ΔT = T_f - T_i = 1811 K - 1825 K = -14 K
q₁ = mCΔT = 575 g × 0.449 J·K⁻¹g⁻¹ × (-14 K) = -361 J = -3.61 kJ
(b) Heat lost on solidifying
(c) Total heat lost
q = q₁ + q₂ = -3.61 kJ - 142.1 kJ = -146 kJ
The heat lost was 146 kJ.
Answer:
A. It measures the [products] / [reactants].
Explanation:
- The reaction quotient aids in figuring out which direction a reaction is likely to proceed, given either the pressures or the concentrations of the reactants and the products.
- It is calculated from the concentration of the products and reactants at mixing up.
- Reaction quotient (Q) = [products] / [reactants]
So, the right choice answer:
A. It measures the [products] / [reactants].
Answer:
this really works https://chem.libretexts.org/Courses/Saint_Marys_College_Notre_Dame_IN/CHEM_122-02_(Under_Construction)/1%3A_Review_from_CHEM_121/1.05%3A_Units%2C_Measurement_Uncertainty%2C_and_Significant_Figures_(Worksheet)
