1) boiling points increase as molecular weight increase and vice versa. This is due to the increase in van der waals forces between molecules.
2) branching decreases the melting and boiling i.e increase in branching decrease boiling point and melting point. This is due to the fact that there are less point of contact between neighbouring molecules, so molecules are farther apart from each other, which means weaker van der waals(London forces) less energy is required to overcome these force of attraction.
3) In homolytic fission each of the fragment retain one of the bonded electron and radicals are made if the molecule is neutral. In heterolytic fission one fragment gets both bonding electron.
The energy for the heterolytic fission is higher because energy is not only needed to break the covalent bond but also to overcome the force of attraction between oppositely charged ions formed.
<span>An element belonging to the halogen family would be expected to have a large ionization energy and a large electron affinity.
Flourine, Chlorine, Bromine, Iodine and astatine are the elements that belongs to the halogen family and mostly they have high values of ionization energy.
The amount of energy released when an electron is added to an atom or molecule to form a negative ion or anion is electron affinity.</span>Chlorine from this family has highest electron affinity.
PH is the test of acidity or basicity of a solution. it follows the formula:
pH = pKa + log [salt] / [acid] where NaF is the salt and HF is the acid in this case.
By literature, Ka of HF is 3.5*10^-4
<span>pKa= -log(Ka)=</span><span> 3.46 </span>
<span>pH = pKa + log [NaF / [HF] </span>
4.05 = 3.46 + log [NaF / [HF]
log [NaF / [HF]<span> = 0.59
</span>
[NaF / [HF] = 3.89
Answer:
0.252 milimoles
Explanation:
To convert mass of a substance to moles it is necessary to use the molar mass of the substance.
The formula of morphine is C₁₇H₁₉NO₃, thus, its molar mass is:
C: 17*12.01g/mol = 204.17g/mol
H: 19*1.01g/mol = 19.19g/mol
N: 1*14g/mol = 14g/mol
O: 3*16g/mol = 48g/mol.
204.17 + 19.19 + 14 + 16 = <em>285.36g/mol</em>
Thus, moles of 71.891 mg = 0.071891g:
0.071891g × (1mol / 285.36g) = 2.5193x10⁻⁴ moles
As 1 mole = 1000 milimoles:
2.5193x10⁻⁴ moles = <em>0.252 milimoles</em>
Answer:o It is important to realise that mixing will be small unless there are electrons in the 4a1 LUMO, this is why NH3 is pyramidal while BH3 is planar! ... This mixing is very strong and stabilises the 3a1 MO substantially and hence NH3 is trigonal pyramidal and not planar.
Explanation:
