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Doss [256]
2 years ago
13

A solution of KMnO4 has an absorbance of 0.539 when measured in the colorimeter. Determine the concentration of the KMnO4 given

the following data for a calibration plot.
Concentration of KMNO4 (M) Absorbance
0.0150 0.081
0.0300 0.159
0.0450 0.260
0.0600 0.334
Chemistry
1 answer:
loris [4]2 years ago
6 0

Answer:

Concentration of unknown solution is 0.0416 M

Explanation:

As we know  

Absorbance is equal to the product of molar absorptivity of KMnO4 m, path length and concentration

From the given set of graphical data, it is clear that the absorbance vs concentration is a straight line.  

From the graph, we can obtain-  

Y = 5.73 X – 0.0065

Absorbance = 0.232

0.232 = 5.73 X – 0.0065

X = 0.0416  

Concentration of unknown solution is 0.0416 M

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Determine the rate law, including the values of the orders and rate law constant, for the following reaction using the experimen
olga55 [171]

Answer: Rate law=k[A]^1[B]^2, order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is 3L^2mol^{-2}s^{-1}

Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

Rate=k[A]^x[B]^y

k= rate constant

x = order with respect to A

y = order with respect to A

n = x+y = Total order

a) From trial 1: 1.2\times 10^{-2}=k[0.10]^x[0.20]^y    (1)

From trial 2: 4.8\times 10^{-2}=k[0.10]^x[0.40]^y    (2)

Dividing 2 by 1 :\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}

4=2^y,2^2=2^y therefore y=2.

b) From trial 2: 4.8\times 10^{-2}=k[0.10]^x[0.40]^y    (3)

From trial 3: 9.6\times 10^{-2}=k[0.20]^x[0.40]^y   (4)

Dividing 4 by 3:\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}

2=2^x,2=2^1, x=1

Thus rate law is Rate=k[A]^1[B]^2

Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.

c) For calculating k:

Using trial 1:  1.2\times 10^{-2}=k[0.10]^1[0.20]^2

k=3 L^2mol^{-2}s^{-1}.



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3 years ago
What do elements in the first two columns of the periodic table have in common?
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Answer: b.) they tend to lose electrons to gain stability

Explanation:

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3 years ago
The particles of a gas are<br> O electrons<br> O atoms or molecules<br> O neutrons<br> O waves
Harrizon [31]
Answer:
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Explanation:
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8 0
2 years ago
How many moles of steam are produced when 5.74 moles of octane (C3H18) react?
jonny [76]

Answer:

51.66 mol H2O (steam)

Explanation:

5.74 mol C3H18 x 18 mol H2O/ 2 mol C3H18 = 51.66 mol H2O (steam)

6 0
2 years ago
An iron(iii) sulfate hydrate is 18.4% water. What is the formula of the hydrate? What is the name of the hydrate?
aleksley [76]

Answer:- Formula of the hydrate is Fe_2(SO_4)_3.5H_2O and it's name is Iron(III)sulfate pentahydrate.

Solution:- As per the given information, there is 18.4% water in the hydrate. If we assume the mass of the hydrate as 100 grams then there would be 18.4 grams of water and 81.6 grams of Iron(III)sulfate present in the hydrate.

Molar mass for Iron(III)sulfate is 399.88 gram per mol and the molar mass for water is 18.02 gram per mol.

We will calculate the moles of Iron(III)sulfate and water present in the compound on dividing their grams by their molar masses as:

81.6gFe_2(SO_4)_3(\frac{1mol}{399.88g})

= 0.204molFe_2(SO_4)_3

18.4gH_2O(\frac{1mol}{18.02g})

= 1.02molH_2O

Now, the next step is to calculate the mol ratio and for this we divide the moles of each by the least one of them means whose moles are less. Here, the moles of Iron(III)sulfate are less than moles of water. So, we divide the moles of each by 0.204.

Fe_2(SO_4)_3=\frac{0.204}{0.204}  = 1

H_2O=\frac{1.02}{0.204} = 5

There is 1:5 mol ratio between Iron(III)sulfate and water. So, the formula of the hydrate is Fe_2(SO_4)_3.5H_2O and the name of the hydrate is Iron(III)sulfate pentahydrate.


3 0
2 years ago
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