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3 years ago

Consider the equations below.

Chemistry

2 answers:

kow [346]3 years ago

8 0

Answer:

Arrow A:

✔ 74.6 kJ

Arrow B:

✔ exothermic

Arrow C:

✔ has a magnitude that is less than that of B

Arrow D:

✔ represents the overall enthalpy of reaction

Explanation:

Elodia [21]3 years ago

6 0

74.6 kJ

exothermic

has a magnitude that is less than that of B

represents the overall enthalpy of reaction

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Find the standard enthalpy of formation of ethylene, C2H4(g), given the following data: C2H4(g) + 3 O2(g) --> 2CO2(g) + 2 H2O

Brums [2.3K]

Answer : The standard enthalpy of formation of ethylene is, 52.4 kJ

Explanation :

According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

The formation reaction of $C_2H_4$ will be,

$2C(s)+2H_2(g)\rightarrow C_2H_4(g)$ $\Delta H_{formation}=?$

The intermediate balanced chemical reaction will be,

(1) $C_2H_4(g)+3O_2(g)\rightarrow 2CO_2(g)+2H_2O(l)$ $\Delta H_1=-1411kJ$

(2) $C(s)+O_2(g)\rightarrow CO_2(g)$ $\Delta H_2=-393.5kJ$

(3) $H_2(g)+\frac{1}{2}O_2(g)\rightarrow H_2O(l)$ $\Delta H_3=-285.8kJ$

Now we will reverse the reaction 1, multiply reaction 2 and 3 by 2 then adding all the equation, we get :

(1) $2CO_2(g)+2H_2O(l)\rightarrow C_2H_4(g)+3O_2(g)$ $\Delta H_1=+1411kJ$

(2) $2C(s)+2O_2(g)\rightarrow 2CO_2(g)$ $\Delta H_2=2\times (-393.5kJ)=-787kJ$

(3) $2H_2(g)+2O_2(g)\rightarrow 2H_2O(l)$ $\Delta H_3=2\times (-285.8kJ)=-571.6kJ$

The expression for enthalpy of formation of $C_2H_4$ will be,

$\Delta H_{formation}=\Delta H_1+\Delta H_2+\Delta H_3$

$\Delta H=(+1411kJ)+(-787kJ)+(-571.6kJ)$

$\Delta H=52.4kJ$

Therefore, the standard enthalpy of formation of ethylene is, 52.4 kJ

7 0

3 years ago

PLEASE HELP!!! 20 POINTS!!!

Sergio [31]

1. True
2. True
3. False
4. True

8 0

4 years ago

Read 2 more answers

51. The radius of gold is 144 pm and the density is 19.32 g/cm3. Does elemental gold have a face-centered cubic structure or a b

Serjik [45]

Answer:

Elemental gold to have a Face-centered cubic structure.

Explanation:

From the information given:

Radius of gold = 144 pm

Its density = 19.32 g/cm³

Assuming the structure is a face-centered cubic structure, we can determine the density of the crystal by using the following:

$a = \sqrt{8} r$

$a = \sqrt{8} \times 144 pm$

a = 407 pm

In a unit cell, Volume (V) = a³

V = (407 pm)³

V = 6.74 × 10⁷ pm³

V = 6.74 × 10⁻²³ cm³

Recall that:

Net no. of an atom in an FCC unit cell = 4

Thus;

$density = \dfrac{mass}{volume}$

$density = \dfrac{ 4 \ atm ( 196.97 \ g/mol) (\dfrac{1 \ mol }{6.022 \times 10^{23} \ atoms})}{6.74 \times 10^{-23} \ cm^3}$

density d = 19.41 g/cm³

Similarly; For a body-centered cubic structure

$r = \dfrac{\sqrt{3}}{4}a$

where;

r = 144

$144 = \dfrac{\sqrt{3}}{4}a$

$a = \dfrac{144 \times 4}{\sqrt{3}}$

a = 332.56 pm

In a unit cell, Volume V = a³

V = (332.56 pm)³

V = 3.68 × 10⁷ pm³

V 3.68 × 10⁻²³ cm³

Recall that:

Net no. of atoms in BCC cell = 2

∴

$density = \dfrac{mass}{volume}$

$density = \dfrac{ 2 \ atm ( 196.97 \ g/mol) (\dfrac{1 \ mol }{6.022 \times 10^{23} \ atoms})}{3.68 \times 10^{-23} \ cm^3}$

density =17.78 g/cm³

From the two calculate densities, we will realize that the density in the face-centered cubic structure is closer to the given density.

This makes the elemental gold to have a Face-centered cubic structure.

3 0

3 years ago

A snowflake contains 2.1 10^18 molecules of water. How many moles of water does it contain?

IgorC [24]

Answer:

divide the # of molecules by avogadros number and get 3.48 x 10^-6

Explanation:

6 0

3 years ago

What would be the major product obtained from hydroboration–oxidation of the following alkenes?

zmey [24]

Answer:

a. 3-methylbutan-2-ol

b. 2-methylcyclohexan-1-ol

Explanation:

For this reaction, we must remember that the hydroboration is an "anti-Markovnikov" reaction. This means that the "OH" will be added at the least substituted carbon of the double bond.

In the case of 2-methyl-2-butene, the double bond is between carbons 2 and 3. Carbon 2 has two bonds with two methyls and carbon 3 is attached to 1 carbon. Therefore the "OH" will be added to carbon three producing 3-methylbutan-2-ol.

For 1-methylcyclohexene, the double bond is between carbons 1 and 2. Carbon 1 is attached to two carbons (carbons 6 and 7) and carbon 2 is attached to one carbon (carbon 3). Therefore the "OH" will be added to carbon 2 producing 2-methylcyclohexan-1-ol.

See figure 1

I hope it helps!

8 0

3 years ago