Answer:

Explanation:
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In this case, since at 60 °C, 108 grams of ammonium bromide are completely dissolved in 100 grams of water for a saturated solution, once it is cooled to 30 °C, wherein only 83.2 grams are completely dissolved in 100 grams of water, the following mass will precipitate:

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The acid dissociation constant of benzoic acid is 6.5 x 10^-5. Therefore, the pH of the benzoic acid solution prior to adding sodium benzoate is:
pH = -log[Ka]
pH = -log (6.5 x 10^-5)
pH = 4.19
The pH of the benzoic acid solution is 4.19 which is acidic, but a weak acid.
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