<u>Answer:</u> The freezing point of solution is 2.6°C
<u>Explanation:</u>
To calculate the depression in freezing point, we use the equation:
Or,
where,
= 
Freezing point of pure solution = 5.5°C
i = Vant hoff factor = 1 (For non-electrolytes)
= molal freezing point depression constant = 5.12 K/m = 5.12 °C/m
= Given mass of solute (anthracene) = 7.99 g
= Molar mass of solute (anthracene) = 178.23 g/mol
= Mass of solvent (benzene) = 79 g
Putting values in above equation, we get:
Hence, the freezing point of solution is 2.6°C
Answer:
ΔH°rxn = - 433.1 KJ/mol
Explanation:
- CH4(g) + 4Cl2(g) → CCl4(g) + 4HCl(g)
⇒ ΔH°rxn = 4ΔH°HCl(g) + ΔH°CCl4(g) - 4ΔH°Cl2(g) - ΔH°CH4(g)
∴ ΔH°Cl2(g) = 0 KJ/mol.....pure element in its reference state
∴ ΔH°CCl4(g) = - 138.7 KJ/mol
∴ ΔH°HCl(g) = - 92.3 KJ/mol
∴ ΔH°CH4(g) = - 74.8 KJ/mol
⇒ ΔH°rxn = 4(- 92.3 KJ/mol) + (- 138.7 KJ/mol) - 4(0 KJ/mol) - (- 74.8 KJ/mol)
⇒ ΔH°rxn = - 369.2 KJ/mol - 138.7 KJ/mol - 0 KJ/mol + 74.8 KJ/mol
⇒ ΔH°rxn = - 433.1 KJ/mol
Answer:
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Answer:
No net change in reaction occurs in this nucleophilic acyl subtitution reaction
Explanation:
Sodium ethoxide in ethanol gives nucleophilic acyl substitution reaction with ethyl-2-methylpropanoate.
Here ethoxide group replaces an ethoxide group from ester through addition-ellimination pathway.
So, ultimately, the product of this reaction is identical with reactant i.e. ethyl-2-methylpropanoate is reproduced.
Hence one might observe no change during reaction as product and reactant of this reaction are same.
Mechanistic pathway has been shown below.
