Chlorofluorocarbons such as CCl2F and CCI,F, have been linked to ozone depletion in Antarctica. In 1994, these gases were found
in quantities of 261 and 509 parts per trillion by volume (World Resources Institute, World resources 1996-97). Compute the molar concentration of these gases under conditions typical of (a) the mid-latitude troposphere (10 °C and 1.0 atm) and (b) the Antarctic stratosphere (200 K and 0.050 atm). Hint: The composition of a mixture of gases can be described by imagining that the gases are separated from one another in such a way that each exerts the same pressure. If one gas is present at very low levels it is common to express its concentration as, for example, ‘x parts per trillion by volume Then the volume of the separated gas at a certain pressure is x x 10-2 of the original volume of the gas mixture at the same pressure. For a mixture of perfect gases, the volume of each separated gas is proportional to its partial pressure in the mixture and hence to the amount in moles of the gas molecules present in the mixture.
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We need to measure 20.0 grams of CaCl₂ to prepare 500 mL of 0.360 M solution.
First, we need to determine the required moles of CaCl₂. We have 500 mL (0.500 L) of a 0.360 M solution (0.360 moles of CaCl₂ per liter of solution).
Then, we will convert 0.180 moles to grams using the molar mass of CaCl₂ (110.98 g/mol).
To prepare the solution, we weigh 20.0 g of CaCl₂ and add it to a beaker with enough distilled water to dissolve it. We stir it, heat it if necessary, and when we have a solution, we transfer it to a 500 mL flask and complete it to the mark with distilled water.
We need to measure 20.0 grams of CaCl₂ to prepare 500 mL of 0.360 M solution.
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