Here are the resonance contributors I found.
Answer:
substances with a higher boiling point are returning back to the flask which allows another substances with the specific context temperature (lower boiling point) to boil over and be purified.
Explanation:
The reason it happens because the lower boiling point substance vaporizes and crosses over while the other substance is waiting for its boiling point to reach
Partial pressure (N2) = mole fraction * total pressure
{ 1 mole of any ideal gas occupy same volume of 1 mole of any other ideal gas under same condition of temperature and pressure so mole fraction in the sample is simply 78.08% = 0.7808 this is because equal volume of each gas has equal moles
partial pressure N2 = 0.7808 * 760 .0
partial pressure = 593.4 mmhg ( 1 torr = 1mmhg )
Because they have similar attractive forces in their molecules