Answer:
Explanation:
Hrxn = -245.6-296.8+396+50.0 = -96.4 (kJ/mol)
Since Grxn = Hrxn - T*Srxn, where T = 298.15K, we have:
Srxn = (Hrxn - Grxn)/T = (-96.4+75.2)× 1000÷298.15 = -71.1 (j/K mol)
Since: Srxn = Sf (SO2) + Sf (SOCl2)- Sf (SO3) - Sf (SCl2),
or: -71.1 = 248.1 + Sf (SOCl2) - 256.7-184,
Sf (SOCl2) = 256.7+184-71.1-248.1 = 121.5 (J/mol*k)
In order to find T such that Grxn = Hrxn - T*Srxn >= 0. since Hrxn is negative and Srxn is positive, Grxn will always be less than zero. Therefore there won't be a temperature point at which the reaction is going to be non-spontaenous