Heating a substance causes molecules to speed up and spread slightly further apart, occupying a larger volume that results in a decrease in density. Cooling a substance causes molecules to slow down and get slightly closer together, occupying a smaller volume that results in an increase in density.
From: www.middleschoolchemistry.com
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First, we need to get n1 (no.of moles of water ): when
mass of water = 0.0203 g and the volume = 1.39 L
∴ n1 = mass / molar mass of water
= 0.0203g / 18 g/mol
= 0.00113 moles
then we need to get n2 (no of moles of water) after the mass has changed:
when the mass of water = 0.146 g
n2 = mass / molar mass
= 0.146g / 18 g/ mol
= 0.008 moles
so by using the ideal gas formula and when the volume is not changed:
So, P1/n1 = P2/n2
when we have P1 = 1.02 atm
and n1= 0.00113 moles
and n2 = 0.008 moles
so we solve for P2 and get the pressure
∴P2 = P1*n2 / n1
=1.02 atm *0.008 moles / 0.00113 moles
= 7.22 atm
∴the new pressure will be 7.22 atm