Charles law gives the relationship between temperature of gas and volume of gas.
It states that for a fixed amount of gas, temperature is directly proportional to volume of gas.
V / T = k
where V- volume , T - temperature and k - constant

parameters for the first instance are on the left side and parameters for the second instance are on the right side of the equation.
T1 = 250 °C + 273 = 523 K
T2 = 150 °C + 273 = 423 K
Substituting the values in the equation,

V = 251 mL
the new volume is 251 mL
Answer:
2.77 mol N
Explanation:
M(N2O) = 2*14 + 16 = 44 g/mol
61.0 g * 1 mol/44g = (61/44) mol N2O
N2O ---- 2N
1 mol 2 mol
(61/44) mol x mol
x = (61/44)*2/1 = 2.77 mol N
The overall reaction is given by:

The fast step reaction is given as:

The slow step reaction is given as:
(slow step
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as
takes place in this reaction.
The expression of rate of formation is:

=
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of
in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of
in terms of reactants is given by
.
Bohr changed the model of the atom by proposing that electrons travelled in circular orbits with specific energy levels.
Answer:
As the axial tilt increases, then the seasonal contrast increases so that winters are colder and summers are warmer in both hemispheres. The northern hemisphere is tipped away from the Sun, producing short days and a low sun angle. What kind of effect does the earth's tilt and subsequent seasons have on our length of daylight (defined as sunrise to sunset). Over the equator, the answer is not much.