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faltersainse [42]
3 years ago
10

Alguien me puede hacer el favor de ayudarme con estos 3 ejercicios de balanceo de ecuaciones por oxido reducción por favor 1. Fe

2O3 + CO → Fe + CO2 2. Al2O3 + C + Cl2 → CO + AlCl3 3. H2S + O2 → SO2 + H2O
Chemistry
1 answer:
kondaur [170]3 years ago
5 0

Answer:

1. Fe₂O₃ + 3CO → 2Fe + 3CO₂

2. Al₂O₃ + 3C + Cl₂ → 3CO + 2AlCl₃

3. 2H₂S + 3O₂ → 2SO₂ + 2H₂O

Explanation:

Para balancear ecuaciones redox se acostumbra a usar el método ion-electrón, hay que determinar qué elemento se oxida y cual se reduce lo que a la vez significa, aumento del número de oxidación o descenso del mismo.

1. Fe₂O₃ + CO → Fe + CO₂

Para este caso, el hierro se reduce, pasando de Fe³⁺ a Fe⁰ o lo que se dice estado fundamental.

Fe³⁺  +  3e⁻  → Fe

El carbono del CO se oxida a CO₂ donde el carbono pasa de C²⁺ a C⁴⁺

C²⁺  →   C⁴⁺ + 2e⁻

Como los electrones quedaron desbalanceados multiplicamos por 2 y 3 las semi reacciones

(Fe³⁺  +  3e⁻  → Fe ) . 2

2Fe³⁺  +  6e⁻  → 2Fe

(C²⁺  →   C⁴⁺ + 2e⁻) . 3

3C²⁺  →   3C⁴⁺ + 6e⁻

Ya podemos balancear la ecuacion final:

Fe₂O₃ + 3CO → 2Fe + 3CO₂

(como ya tenemos 2 atomos de hierro en el oxido, no haría falta agregar el 2 en la estoquiometría)

2. Al₂O₃ + C + Cl₂ → CO + AlCl₃

En este caso el carbono se oxida, y el cloro se reduce

C →  C²⁺  +  2e⁻

Cl₂ + 2e⁻ → 2Cl⁻

Como el cloro es una molécula diatómica por cada cloro que se reduce, tendremos dos cloruros, tomando los 2 electrones que libera el C.

En este caso los electrones están balanceados

Al₂O₃ + C + Cl₂ → CO + 2AlCl₃

Han quedado desbalanceados el C y el O, asi que no queda otra que completar con la estequiometría

Al₂O₃ + 3C + Cl₂ → 3CO + 2AlCl₃

3.  H₂S + O₂ → SO₂ + H₂O

El O₂ se está reduciendo, pasando de 0 a -2

El S del ácido se oxida de +2 a +4

O₂ + 4e⁻ → 2O⁻²

Son dos atomos de O, que cada átomo puede atrapar dos electrones, por ende, consigue enlazar 4 electrones en total

S⁺²  → S⁴⁺ + 2e⁻

Como los electrones quedaron desbalanceados, completamos multiplicando la segunda semi reaccion x2

2S⁺²  → 2S⁴⁺ + 4e⁻

O₂ + 4e⁻ → 2O⁻²

2H₂S + O₂ → 2SO₂ + 2H₂O

Ya que el oxigeno quedó desbalanceado en el lado producto, completamos con la estoquimetría

2H₂S + 3O₂ → 2SO₂ + 2H₂O

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