Answer:
Y is a 3-chloro-3-methylpentane.
The structure is shown in the figure attached.
Explanation:
The radical chlorination of 3-methylpentane can lead to a tertiary substituted carbon (Y) and to a secondary one (X).
The E2 elimination mechanism, as shown in the figure, will happen with a simulyaneous attack from the base and elimination of the chlorine. This means that primary and secondary substracts undergo the E2 mechanism faster than tertiary substracts.
Answer:
Explanation:
Hello,
In this case, for a concentration of 0.42 M of benzoic acid whose Ka is 6.3x10⁻⁵ in 0.33 M sodium benzoate, we use the Henderson-Hasselbach equation to compute the required pH:
![pH=pKa+log(\frac{[base]}{[acid]} )](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29)
Whereas the concentration of the base is 0.33 M and the concentration of the acid is 0.42 M, thereby, we obtain:
![pH=-log(Ka)+log(\frac{[base]}{[acid]} )\\\\pH=-log(6.3x10^{-5})+log(\frac{0.33M}{0.42M} )\\\\pH=4.1](https://tex.z-dn.net/?f=pH%3D-log%28Ka%29%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29%5C%5C%5C%5CpH%3D-log%286.3x10%5E%7B-5%7D%29%2Blog%28%5Cfrac%7B0.33M%7D%7B0.42M%7D%20%29%5C%5C%5C%5CpH%3D4.1)
Regards.
When the balanced equation for this reaction is:
2Fe + 3H2O → Fe2O3 + 3H2
and according to the vapour pressure formula:
PV= nRT
when we have P is the vapor pressure of H2O= 0.121 atm
and V is the volume of H2O = 4.5 L
and T in Kelvin = 52.5 +273 = 325.5 K
R= 0.08205 atm-L/g mol-K
So we can get n H2O
So, by substitution:
n H2O = PV/RT
= (0.121*4.5)/(0.08205 * 325.5) = 0.02038 gmol
n Fe2O3 = 0.02038 * (1Fe2O3/ 3H2O) = 0.00679 gmol
Note: we get (1FeO3/3H2O) ratio from the balanced equation.
we can get the Mass of Fe2O3 from this formula:
Mass = number of moles * molecular weight
when we have a molecular weight of Fe2O3 = 159.7
= 0.00679 * 159.7 = 1.084 g
∴ 1.084 gm of Fe2O3 will produced
