Answer:
Sulfur: -1
Carbon: 0
Nitrogen: 0
Explanation:
The thiocyanate ion SCN- can have only two resonance structures, which are:
S - C ≡ N <--------> S = C = N
In the first structure, we have one single bond and one triple bond, in this case, the negative charge is located in the sulfur. This is because Sulfur have 6 electrons and those electrons are present in the atom, (see picture below), and counting the electron that is sharing with the Carbon, the total electrons that sulfur has is 7 (It has one more than usual). Carbon and nitrogen are already stable with 0 of formal charge, because carbon can only have 4 electrons which 1 is sharing with sulfur and the other 3 with the nitrogen, and nitrogen have 5 electrons, three sharing with carbon and the other two kept it for itself.
In the second structure, the negative charge of the sulfur is transfered to the nitrogen, meaning that it has 6 electrons the nitrogen (formal charge -1) and carbon and sulfur with 4 and 6 electrons respectively.
Between these two structures, the most stable is the first one basically because Sulfur is a better nucleophile than the Nitrogen, and can form stronger hydrogen bond in acid, giving more stable structure.
Answer:
The hydrolysis in aqueous HCl of compound A can lead to the formation of a carboxylic acid and an alcohol.
Explanation:
The picture shows the structures of compound A, benzoncaine and the possible products of the proposed reaction.
The acidic hydrolysis is the inverse of the esterification reaction. Therefore, the ester group of compund A will react to form the equivalent carboxylic acid and alcohol.
In order to form benzocaine, the hydrolysis happens in with the nitrile group.
