In the image below, the truck and bus have the same mass and are
1 answer:
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Answer: Option (B) is the correct answer.
Explanation:
According to Le Chatelier's principle, any disturbance causes in an equilibrium reaction will shift the equilibrium in a direction that will oppose the change.
For example,
When we increase the temperature then the reaction will shift in a direction where there will be decrease in temperature.
This, means that the reaction will shift in the backward direction.
Thus, we can conclude that if the reaction is at equilibrium and the temperature increases, the equilibrium will shift so that there is more nitrogen dioxide.
The provided information are:
volume of 0.85 M lactic acid = 225 ml
volume of 0.68 M sodium lactate = 435 ml
Ka of the lactate buffer = 1.38 x 10⁻⁴
The equation for dissociation of lactic acid is:
CH₃CH(OH)COOH(aq) + H₂O ⇄ CH₃CH(OH)COO⁻(aq) + H₃O⁺(aq)
The pH of buffer is calculated from Henderson-Hasselbalch equation, which is:
pH = pKa + log![\frac{[conjugated base]}{[Acid]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5Bconjugated%20base%5D%7D%7B%5BAcid%5D%7D%20)
pKa = - log Ka = - log (1.38 x 10⁻⁴) = 3.86
The number of moles of lactic acid and lactate are as follows:
n (Lactic acid) = 225 ml x 0.85 mmol/ml = 191.25 mmol
n (Lactate) = 435 ml x 0.68 mmol/ml = 295.8 mmol
The number of moles of lactic acid and lactate in total volume of the solution:
[CH₃CH(OH)COOH] = n (lactic acid) / 660 ml = 191.25 mmol / 660 ml = 0.29 M
[CH₃CH(OH)COO⁻] = n (lactate) / 660 ml = 0.45 M
pH = 3.86 + log
= 3.86 + 0.191 = 4.05
So the pH of given solution is 4.05
volume of 0.85 M lactic acid = 225 ml
volume of 0.68 M sodium lactate = 435 ml
Ka of the lactate buffer = 1.38 x 10⁻⁴
The equation for dissociation of lactic acid is:
CH₃CH(OH)COOH(aq) + H₂O ⇄ CH₃CH(OH)COO⁻(aq) + H₃O⁺(aq)
The pH of buffer is calculated from Henderson-Hasselbalch equation, which is:
pH = pKa + log
pKa = - log Ka = - log (1.38 x 10⁻⁴) = 3.86
The number of moles of lactic acid and lactate are as follows:
n (Lactic acid) = 225 ml x 0.85 mmol/ml = 191.25 mmol
n (Lactate) = 435 ml x 0.68 mmol/ml = 295.8 mmol
The number of moles of lactic acid and lactate in total volume of the solution:
[CH₃CH(OH)COOH] = n (lactic acid) / 660 ml = 191.25 mmol / 660 ml = 0.29 M
[CH₃CH(OH)COO⁻] = n (lactate) / 660 ml = 0.45 M
pH = 3.86 + log
So the pH of given solution is 4.05