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a_sh-v [17]
2 years ago
5

If 52.5 mL of lead(II) nitrate solution reacts completely with excess sodium iodide solution to yield 0.248 g of precipitate, wh

at is the molarity of lead(II) ion in the original solution
Chemistry
1 answer:
user100 [1]2 years ago
7 0

Explanation:

The volume of given lead nitrate solution is:

52.5 mL.

The amount of lead iodide formed is ---0.248 g.

To get the molarity of lead (II) ion follow the below-shown procedure:

The number of moles of lead iodide formed is:

number of moles of lead iodide(n)=mass of lead iodide/its molecular mass\\n=0.248 g/461.01g/mol\\n=0.000537mol

0.000537 mole of lead iodide contains --- 0.000537 moles of lead (II) ion.

Thus, the number of moles are there, volume is there, and to get the molarity of lead (II) ion use the formula:

Molarity=\frac{number of moles}{volume in L.} \\M=0.000537 mol / 0.0525 L.\\M=0.0102mol/L

Molarity of lead iodide is --- 0.0102 M.

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2 years ago
State the five the five basic assumptions of the kinetic-molecular theory.
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Answer:

The primary assumptions are as follows:

Any gas is a collection of innumerable number of minuscule particles which are known as molecules according to Avogadro’s law.

There are no forces of attraction or repulsion among the particles or between the molecules and the surroundings.

The gas particles are always at straight, rapid, fast & random motion resulting in inevitable collisions with other particles and the surroundings that changes direction of motion.

Since the particle are spherical, solid and elastic the collisions involving them are elastic in nature as well i.e their kinetic energy is conserved even after collisions.

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In some books two other assumptions are given as well:

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2. Pressure of gas is result of the continuous clash of the particles with the wall of the container.

or

The simplest kinetic model is based on the assumptions that: (1) the gas is composed of a large number of identical molecules moving in random directions, separated by distances that are large compared with their size; (2) the molecules undergo perfectly elastic collisions (no energy loss) with each other and with the walls of the container, but otherwise do not interact; and (3) the transfer of kinetic energy between molecules is heat. These simplifying assumptions bring the characteristics of gases within the range of mathematical treatment.

Such a model describes a perfect gas and is a reasonable approximation to a real gas, particularly in the limit of extreme dilution and high temperature. Such a simplified description, however, is not sufficiently precise to account for the behaviour of gases at high densities.

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7 0
2 years ago
500 mL of a solution contains 1000 mg of CaCl2. Molecular weight of CaCl2 is 110 g/mol. Specific gravity of the solution is 0. C
dangina [55]

Answer:

a) 0,2% w/v

b) r=500

c) 0,0182 M

d) 0,0145 m

e) 0,0137 equivalents

Explanation:

a) % w/v means mass of solute in grams per 100 mililiter of solution. Thus:

%w/v= \frac{1,000 g CaCl2}{500mL}×100 = 0,2%w/v

b) Ratio strength is a way to express concentration.  For w/v is in 1g of solute <em>r</em> mililiters of solution have. Thus, r = 500 because we have in the first 1 g of CaCl₂ in 500 mL of solution.

c) Molarity is moles of solute per liter of solution, thus:

1,000 g of CaCl₂ × \frac{1mol}{110g} = 9,09×10⁻³ moles of CaCl₂

500 mL of solution  × \frac{1L}{1000mL} = 0,500 L of solution

M = \frac{9,09x10^{-3} moles }{0,500 L} = 0,0182 M

d) Molality is moles of solute per kg of solution.

Specific gravity is the ratio between density of the solution and density of a reference substance (Usually water). With a specific gravity of 0,8:

kg of solution = 0,500 L of solution × \frac{0,8 kg}{1L} =<em> </em><em>0,625 kg of solution</em>

m = \frac{9,09x10^{-3}moles }{0,625 kg} = 0,0145 m

e)  In a salt, equivalents are the number of moles ables to replace one mole of charge. In CaCl₂ is ¹/₂ because with  ¹/₂ moles of CaCl₂ it is possible to replace 1 mole of charges. Thus, in 1,5 L there are:

1,5 L ×\frac{0,0182 CaCl2 moles}{1L} × \frac{1equivalent}{2 moles} = 0,0137 equivalents

I hope it helps!

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