<span>The problem has to do with oxidation states of the matter. The oxidation state of oxygen will always be -2 with the exception of peroxides which will have a state of -1. The overall balanced state of chemical compounds will be 0, so the oxidation state of Mn in MnO2 will be +4. The oxidation state of MnO4- will then be +7 to balance out to the negative one charge. The state change from +4 to +7 is 3, thus three electrons have to be lost in order for this to happen; a loss of a charge of -3 results in an increase of charge of 3. Oxidation is always the process of 'losing' electrons.
</span><span>E] MnO2(s) MnO4-(aq</span>
Its most significant when all other forces are absent
Temperature can change a reaction rate because adding or taking away heat means energy is being added or taken away. When energy is added, the particles speed up, so there is a greater chance of the reactants colliding to form the products, which increases the reaction rate. When energy is taken away, the particles more slower, so they don't collide as easily, which slows down the reaction rate.
Therefore, the answer is D.
Answer : The enthalpy of the reaction is, -2552 kJ/mole
Explanation :
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
The given enthalpy of reaction is,

The intermediate balanced chemical reactions are:
(1)

(2)

(3)

(4)

Now we have to revere the reactions 1 and multiple by 2, revere the reactions 3, 4 and multiple by 2 and multiply the reaction 2 by 2 and then adding all the equations, we get :
(when we are reversing the reaction then the sign of the enthalpy change will be change.)
The expression for enthalpy of the reaction will be,



Therefore, the enthalpy of the reaction is, -2552 kJ/mole