1 2.2.3 Quiz: Shapes of Molecules

Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A soluti

koban [17]

Answer:

1) 2.0 g

2) 0 g

3) 4.17 g

4) 2.57 g

Explanation:

First of all, we need to know the compounds and the reaction. The ion carbonate is $CO3^{-2}$ , and the ion nitrate is $NO3^{-}$ .

Sodium is in group 1, so it must lose one electron to be stable, and be the cation $Na^{+}$ . Silver has only one electron too, so the cation will be $Ag^{+}$ .

To form the chemical compounds, first we put the cation, then the anion, and change their charges without the signal:

Sodium carbonate: Na2CO3

Silver nitrate: AgNO3

Silver carbonate: Ag2CO3

Sodium nitrate: NaNO3

The balanced reaction will be:

Na2CO3 + 2 AgNO3 --> Ag2CO3 + 2 NaNO3

Now, we must check the stoichiometry, which will be 1:2:1:2 (always in number of moles)

The question wants to know the mass value, so we need to know the molar mass of these compounds. Checking the periodic table will see that:

Na = 23 g/mol, C = 12 g/mol, N = 14 g/mol, O = 16 g/mol, Ag = 108 g/mol

So the molar mass of the compounds must be:

Na2CO3 = 106 g/mol (2x23 + 12 + 3x16)

AgNO3 = 170 g/mol (108 + 14 + 3x16)

Ag2CO3 = 276 g/mol (2x108 + 12 + 3x16)

NaNO3 = 85 g/mol

We have a mixture of the reactants, so one probably would be in excess, so, first will need to test. Let's do the stoichiometry calculus using silver nitrate as the limit, so:

1 mol of Na2CO3 ---------- 2 mol of AgNO3

106 g ------------------------------ 2x170 = 340 g

x ------------------------------------ 5.14 g

By a simple direct three rule:

340x = 544.84

x = 1.6 g of Na2CO3

That means that for this reaction, we only need 1.6 g of Na2CO3 to react with 5.14 of AgNO3. How we have 3.60 g of Na2CO3, it is on excess, and all the AgNO3 will be consumed.

1) The mass of Na2CO3 that remains after the reaction will be the initial less the mass that reacted:

m = 3.6 - 1. 6 = 2.0 g

2) All the AgNO3 reacted, so there isn't a mass present after the reaction.

m = 0 g

3) Now, doing the stoichiometry calculus between AgNO3 and Ag2CO3

2 moles of AgNO3 ------------- 1 mol of Ag2CO3

2x170 g ------------------------------- 276 g

5.14 g --------------------------------- x

By a simple direct three rule:

340x = 1418.64

x = 4.17 g of Ag2CO3

4) Now, doing the stoichiometry calculus between AgNO3 and NaNO3

2 moles of AgNO3 ----------------------- 2 moles of NaNO3

2x170 g ---------------------------------------- 2x85 g

5.14 g ------------------------------------------- x

By a simple direct three rule:

340x = 873.8

x = 2.57 g

8 0

2 years ago

Describe what happens in the cell before the chemical reaction.

Zina [86]

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Answer:

Chemical reactions that take place inside living things are called biochemical reactions. The sum of all the biochemical reactions in an organism is referred to as metabolism. Metabolism includes both exothermic (heat-releasing) chemical reactions and endothermic (heat-absorbing) chemical reactions.

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6 0

3 years ago

A student is given a 2.002 g sample of unknown acid and is told that it might be butanoic acid, a monoprotic acid (HC4H7O2, equa

Elina [12.6K]

Answer: The identity of the unknown acid is butanoic acid or ascorbic acid.

Explanation:

To calculate the number of moles for given molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in L)}}$

Molarity of NaOH solution = 0.570 M

Volume of solution = 39.55 mL

Putting values in above equation, we get:

$0.570M=\frac{\text{Moles of NaOH}\times 1000}{39.55}\\\\\text{Moles of NaOH}=\frac{0.570\times 39.55}{1000}=0.0225mol$

The chemical equation for the reaction of NaOH and monoprotic acid follows:

$NaOH+HX\rightarrow NaX+H_2O$

By Stoichiometry of the reaction:

1 mole of NaOH reacts with 1 mole of HX

So, moles of monoprotic acid = 0.0225 moles

The chemical equation for the reaction of NaOH and diprotic acid follows:

$2NaOH+H_2X\rightarrow 2NaX+2H_2O$

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of diprotic acid

So, moles of diprotic acid = $\frac{0.0225}{2}=0.01125moles$

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

For butanoic acid:

Mass of butanoic acid = 2.002 g

Molar mass of butanoic acid = 88 g/mol

Putting values in above equation, we get:

$\text{Moles of butanoic acid}=\frac{2.002g}{88g/mol}=0.02275mol$

For L-tartaric acid:

Mass of L-tartaric acid = 2.002 g

Molar mass of L-tartaric acid = 150 g/mol

Putting values in above equation, we get:

$\text{Moles of L-tartaric acid}=\frac{2.002g}{150g/mol}=0.0133mol$

For ascorbic acid:

Mass of ascorbic acid = 2.002 g

Molar mass of ascorbic acid = 176 g/mol

Putting values in above equation, we get:

$\text{Moles of ascorbic acid}=\frac{2.002g}{176g/mol}=0.01137mol$

As, the number of moles of butanoic acid and ascorbic acid is equal to the number of moles of acid getting neutralized.

Hence, the identity of the unknown acid is butanoic acid or ascorbic acid.

5 0

3 years ago

Would you expect the wavelength of maximum absorbance for [Cu(NH3)4]2+ to be greater than or less than the wavelength of maximum

DENIUS [597]

Answer:

Less

Explanation:

Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:

The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.

The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand

A partial spectrochemical series listing of ligands from small Δ to large Δ:

I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO

Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.

7 0

3 years ago

What does cellular respiration do?

Anton [14]

I believe the answer is A the 1st one

7 0

3 years ago