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Nezavi [6.7K]
3 years ago
5

When pH changes from 6 to 3, how many times does acidity increase?

Chemistry
1 answer:
photoshop1234 [79]3 years ago
8 0

Since a pH of 3 is three numbers higher than a pH of 6, we can find the change in acidity by taking 10 to the third power. The solution with a pH of 3 is 1000 times more acidic than the solution with a pH of 6.

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CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at 25 ∘C under these conditions: PCO2PCCl4PCOCl2===0.140 atm0.185 atm0.7
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<u>Answer:</u> The \Delta G for the reaction is 54.425 kJ/mol

<u>Explanation:</u>

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\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]

For the given equation:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]

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Conversion factor used = 1 kJ = 1000 J

The expression of K_p for the given reaction:

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p_{COCl_2}=0.735atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.185atm

Putting values in above equation, we get:

K_p=\frac{(0.735)^2}{0.410\times 0.185}\\\\K_p=20.85

To calculate the gibbs free energy of the reaction, we use the equation:

\Delta G=\Delta G^o+RT\ln K_p

where,

\Delta G = Gibbs' free energy of the reaction = ?

\Delta G^o = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[25+273]K=298K

K_p = equilibrium constant in terms of partial pressure = 20.85

Putting values in above equation, we get:

\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(20.85))\\\\\Delta G=54425.26J/mol=54.425kJ/mol

Hence, the \Delta G for the reaction is 54.425 kJ/mol

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