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zalisa [80]
3 years ago
11

Suppose a molecule with six electron groups is confined to two dimensions and has a hexagonal planar electron geometry. A molecu

le with six electron groups arranged in a hexagonal planar geometry. The top and bottom groups are labeled 1 and 4, respectively. The two groups next to 1 are labeled 2 and the two groups next to 4 are labeled 3. If two of the six groups are lone pairs, where would they located?
Chemistry
1 answer:
Tanya [424]3 years ago
4 0

Answer:

Above and below the plane of a square

Explanation:

The number of electron groups often determine the shape of a molecule. When we have a coordination number of six, one of the possible arrangement of groups is the hexagonal planar geometry. In this arrangement, six electron groups are arranged in the same plane.

If two among the groups are replaced by lone pairs, the substituents will arrange themselves at the corners of a square while the lone pairs will be found above and below the plane of the square. This is the square planar geometry.

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Use the provided reduction potentials to calculate ArGº for the following balanced redox reaction: Pb2+(aq) + Cu(s) → Pb(s) + Cu
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Answer : The correct option is, +91 kJ/mole

Solution :

The balanced cell reaction will be,  

Cu(s)+Pb^{2+}(aq)\rightarrow Cu^{2+}(aq)+Pb(s)

Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.

First we have to calculate the standard electrode potential of the cell.

E^0_{[Pb^{2+}/Pb]}=-0.13V

E^0_{[Cu^{2+}/Cu]}=+0.34V

E^0_{cell}=E^0_{cathode}-E^0_{anode}

E^0_{cell}=E^0_{[Pb^{2+}/Pb]}-E^0_{[Cu^{2+}/Cu]}

E^0_{cell}=-0.13V-(0.34V)=-0.47V

Now we have to calculate the standard Gibbs free energy.

Formula used :

\Delta G^o=-nFE^o_{cell}

where,

\Delta G^o = standard Gibbs free energy = ?

n = number of electrons = 2

F = Faraday constant = 96500 C/mole

E^o = standard e.m.f of cell = -0.47 V

Now put all the given values in this formula, we get the Gibbs free energy.

\Delta G^o=-(2\times 96500\times (-0.47))=+90710J/mole=+90.71kJ/mole\approx +91kJ/mole

Therefore, the standard Gibbs free energy is +91 kJ/mole

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3 years ago
What is the solute when stirring salt in water until the salt disappears?
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Answer:

The solute is the substance being dissolved.

The solvent is the substance dissolving the solute.

Therefore, the salt is the solute and the water is the solvent.

Explanation:

The salt is the solute.

3 0
3 years ago
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First we have to calculate the moles of gas.

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Now we have to calculate the molecular weight of a gas.

Formula used :

\text{Moles of gas}=\frac{\text{Mass of a gas}}{\text{Molecular weight of a gas}}

Now put all the given values in this formula, we get the molecular weight of a gas.

0.0446mole=\frac{5.75g}{\text{Molecular weight of a gas}}

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3 years ago
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