From the equation:
4mol Li react with 1 mol O2
Molar mass Li = 7g/mol
mol in 84g Li = 84/7 = 12 mol Li
From the equation - 12 mol Li will react with 3 mol O2
At STP 1 mol O2 has volume = 22.4L
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At STP 3 mol O2 has volume = 3*22.4 = 67.2L O2 gas will react. </span>
Answer:but-1-ene
Explanation:This is an E2 elimination reaction .
Kindly refer the attachment for complete reaction and products.
Sodium tert-butoxide is a bulky base and hence cannot approach the substrate 2-chlorobutane from the more substituted end and hence major product formed here would not be following zaitsev rule of elimination reaction.
Sodium tert-butoxide would approach from the less hindered side that is through the primary centre and hence would lead to the formation of 1-butene .The major product formed in this reaction would be 1-butene .
As the mechanism of the reaction is E-2 so it will be a concerted mechanism and as sodium tert-butoxide will start abstracting the primary hydrogen through the less hindered side simultaneously chlorine will start leaving. As the steric repulsion in this case is less hence the transition state is relatively stabilised and leads to the formation of a kinetic product 1-butene.
Kinetic product are formed when reactions are dependent upon rate and not on thermodynamical stability.
2-butene is more thermodynamically6 stable as compared to 1-butene
The major product formed does not follow the zaitsev rule of forming a more substituted alkene as sodium tert-butoxide cannot approach to abstract the secondary proton due to steric hindrance.
Answer:
a) ammonium ion
b) amide ion
Explanation:
The order of decreasing bond angles of the three nitrogen species; ammonium ion, ammonia and amide ion is NH4+ >NH3> NH2-. Next we need to rationalize this order of decreasing bond angles from the valence shell electron pair repulsion (VSEPR) theory perspective.
First we must realize that all three nitrogen species contain a central sp3 hybridized carbon atom. This means that a tetrahedral geometry is ideally expected. Recall that the presence of lone pairs distorts molecular structures from the expected geometry based on VSEPR theory.
The amide ion contains two lone pairs of electrons. Remember that the presence of lone pairs causes greater repulsion than bond pairs on the outermost shell of the central atom. Hence, the amide ion has the least H-N-H bond angle of about 105°.
The ammonia molecule contains one lone pair, the repulsion caused by one lone pair is definitely bless than that caused by two lone pairs of electrons hence the bond angle of the H-N-H bond in ammonia is 107°.
The ammonium ion contains four bond pairs and no lone pair of electrons on the outermost nitrogen atom. Hence we expect a perfect tetrahedron with bond angle of 109°.
