Hi, here is a basic summary of what we did in a lab; there were 3 reactions: The procedure: Reaction 1: Solid sodium hydroxide dissolves in water to form an aqueous solution of ions. NaOH(s)-> Na+(aq) + OH-(aq) ΔH1=-34.121kJ Reaction 2: Solid sodium hydroxide reacts with an aqueous solution of HCl to form water and an aqueous solution of sodium chloride. NaOH(s) + H+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH2=-83.602kJ Reaction 3: An aqueous solution of sodium hydroxide reacts with an aqueous solution of HCl to form water an an aqueous solution of sodium chloride. H+(aq) + OH-(aq) + Na+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH3= -50.2kJ The ΔH values were calculated by dividing the heat gained by the number of moles (each reaction had 0.05moles of NaOH) The problem: Net ionic equations for reaction 2 & 3: 2: NaOH(s) + H+(aq) -> H2O + Na+(aq) 3: H+(aq) + OH-(aq) -> H2O i) In reaction 1, ΔH1 represents the heat evolved as solid NaOH dissolves. Look at the net ionic equations for reactions 2 and 3 and make similar statements as to what ΔH2 and ΔH3 represent. ii) Compare ΔH2 with (ΔH1 + ΔH3). Explain in sentences the similarity between these two values by using your answer to #5 above. Attempt at answering: i) Firstly, ΔH2 represents the heat evolved as the hydrogen ion displaces the sodium ion, creating a single displacement reaction. ΔH3 represents the heat evolved as the hydrogen and hydroxide ion form water via a neutralization reaction. ii) ΔH2 is equal to (or supposed to be, this is a source of error while calculating) (ΔH1 + ΔH3). The similarity between these two values is that .. (this is where I get confused!)
Source https://www.physicsforums.com/threads/calorimetry-help-chemistry.399653/
The correct answer for the question that is being presented above is this one:
Given that:
delta Tb = Kbm Kb H2O = 0.52 degrees C/m
<span>delta Tf = Kfm Kf H2O = 1.86 degrees C/m
</span>
We need to know the formula for Molality.
molality = mol solute / kg solvent
<span>We are given the amount of solute in grams
Since amount of solute is given in moles, we have to convert 25 g NaCl to moles. Divide by molar mass. </span>
<span>25 g NaCl / 58.5 g/mol = 0.427 mol </span>
<span>Then, use the formula for molality. </span>
<span>molality = mol solute / kg solvent </span>
<span>= 0.427 / 1 </span>
<span>= 0.427 m </span>
<span>Use now the formula to get the boiling point.</span>
<span>delta Tb = Kbm </span>
<span>= (0.52)(0.427) </span>
<span>= 0.22C </span>
C; The Valence electrons spend more time around the atom of F
The body gets rid of acid in a chemical pathway that requires oxygen. The correct answer is B, oxygen.
Problem One
You will use both m * c * deltaT and H = m * heat of fusion.
Givens
m = 12.4 grams
c = 0.1291
t1 = 26oC
t2 = 1204
heat of fusion (H_f) = 63.5 J/grams.
Equation
H = m * c * deltaT + m * H_f
Solution
H = 12.4 * 0.1291 * (1063 - 26) + 12.4 * 63.5
H = 1660.1 + 787.4
H = 2447.5 or 2447.47 is the exact answer. I have to leave the rounding to you. I have no idea where to round it although I suspect 2450 would be right for 3 sig digs.
Problem Two
Formula and Givens
t1 = 14.5
t2 = 50.0
E = 5680
c = 4.186
m = ??
E = m c * deltaT
Solution
5680 = m * 4.186 * (50 - 14.5)
5680 = m * 4.186 * (35.5)
5680 = m * 148.603 * m
m = 5680 / 148.603
m = 38.22 grams That isn't very much. Be very sure you are working in joules. You'd leave that many grams in the kettle after drying it thoroughly.
m = 38.2 to 3 sig digs.
