Answer:
Longer hydrocarbon molecules have a stronger intermolecular force. More energy is needed to move them apart so they have higher boiling points . This makes them less volatile and therefore less flammable
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
Enthalpy of formation is calculated by subtracting the total enthalpy of formation of the reactants from those of the products. This is called the HESS' LAW.
ΔHrxn = ΔH(products) - ΔH(reactants)
Since the enthalpies are not listed in this item, from reliable sources, the obtained enthalpies of formation are written below.
ΔH(C2H5OH) = -276 kJ/mol
ΔH(O2) = 0 (because O2 is a pure substance)
ΔH(CO2) = -393.5 kJ/mol
ΔH(H2O) = -285.5 kJ/mol
Using the equation above,
ΔHrxn = (2)(-393.5 kJ/mol) + (3)(-285.5 kJ/mol) - (-276 kJ/mol)
ΔHrxn = -1367.5 kJ/mol
<em>Answer: -1367.5 kJ/mol</em>
Answer:
Explanation:
Primary and secondary succession occur after both human and natural events that cause drastic change in the makeup of an area. Primary succession occurs in areas where there is no soil and secondary succession occurs in areas where there is soil.
In primary succession, newly exposed or newly formed rock is colonized by living things for the first time. In secondary succession, an area previously occupied by living things is disturbed—disrupted—then recolonized following the disturbance.
Hope this helped :)
-<em>Akito</em>
Answer:
d. IF3
Explanation:
The Octet rule posits that atoms gain, atom lose, or share electrons in order to have a full valence shell of 8 electrons. This statement occurs when atoms also combine to form molecules until they attain or share eight valence electrons either by losing or gaining eletrons.
From the given options, a valid Lewis structure that cannot be drawn without violating the octet rule is IF3
