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NNADVOKAT [17]
3 years ago
13

Carbon monoxide and chlorine gas react to form phosgene:

Chemistry
1 answer:
Ad libitum [116K]3 years ago
8 0

Answer:

XCOCl₂ = 0.25

Explanation:

Let's write the reaction again:

CO(g) + Cl₂(g) -----> COCl₂(g)      Kp = 3.10

With this reaction, we can write the Kp expression:

Kp = PpCOCl₂ / PpCO * PpCl₂

As the pressure are in Torr, we can work these pressure in Atmosphere instead of Torr, and it would be easier cause it would be lower numbers. Remeber that 1 atm is 760 Torr. So Doing this we have:

PpCO = 270 * 1/760 = 0.36 atm

PpCl₂ = 257 / 760 = 0.34 atm

Now, we can write an ICE chart with pressures, so we can know the pressure of COCl₂

         CO(g) + Cl₂(g) -----> COCl₂(g)      Kp = 3.10

I:         0.36     0.34               0

C:          -x          -x                +x

E:        0.36-x   0.34-x           x

Replacing in the Kp expressio:

3.1 = x / (0.36-x)(0.34-x)

Solving for x we have:

3.1 = x / (0.1224 - 0.7x + x²)

3.1(0.1224 - 0.7x + x²) = x

0.3794 - 2.17x + 3.1x² = x

3.1x² - 3.17x + 0.3794 = 0

Now, using the quadratic formula to solve for x, we have:

x = 3.17 ±√(3.17)² - 4*3.1*0.3794 / 2 * 3.1

x = 3.17 ±√10.0489 - 4.7046 / 6.2

x = 3.17 ±√5.3443 / 6.2

x = 3.17 ± 2.3118 / 6.2

x₁ = 0.88

x₂ = 0.14

Using the lowest value of x, (because if we use the highest then the partial pressure of the reactants will give a negative value) we have that the partial pressure of COCl₂ would be 0.14 atm

Now that we have this value, we can calculate the partial pressure at equilibrium of the reactants:

PpCO = 0.36 - 0.14 = 0.22 atm

PpCl₂ = 0.34 - 0.14 = 0.20 atm

Now with these values, we can finally calculate the mole fraction of COCl₂ in equilibrium by using this expression:

XCOCl₂ = PCOCl₂ / Pt

And Pt is the total pressure of all species in reaction so:

Pt = 0.22 + 0.2 + 0.14 = 0.56 atm

Finally, the mole fraction:

XCOCl₂ = 0.14 / 0.56

<h2>XCOCl₂ = 0.25</h2>
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Answer:

1) <u>16.8 L CO2</u>

<u>2) 36.96 L NH3</u>

<u>3) </u> <u>9.88 L CO2 </u>

<u>4) 56.99 L H2O</u>

Explanation:

How many liters of carbon dioxide gas will be produced when 75.0 g of calcium carbonate decomposes to form calcium oxide when at STP?

CaCO3 → CaO + CO2

Moles calcium carbonate = 75.0 grams / 100.09 g/mol

Moles calcium carbonate = 0.750 moles

For 1 mol CaCO3 we'll have 1 mol CaO and 1 mol CO2

For 0.750 moles CaCO3 we'll have 0.750 moles CO2

1 mol = 22.4 L

0.750 moles CO2 = 0.750 *22.4 L =<u> 16.8 L CO2</u>

2. Hydrogen gas reacts with 23.1 g of nitrogen gas to produce ammonia (NH3). What volume of ammonia will be produced at STP?

3H2 + N2 → 2NH3

Moles N2 = 23.1 grams / 28.0 g/mol

Moles N2 = 0.825 moles

For 3 moles H2 we need 1 mol N2 to produce 2 moles NH3

For 0.825 moles N2 we'll have 2*0.825 = 1.65 moles NH3

1 mol = 22.4 L

1.65 mol = 1.65 * 22.4 L = <u>36.96 L NH3</u>

<u />

<u />

3. Iron (III) oxide reacts with carbon monoxide to form iron and carbon dioxide. How many liters of carbon dioxide will be produced from 23.5 g of iron (III) oxide when at STP?

Fe2O3 + 3CO → 2Fe + 3CO2

Moles Fe2O3 = 23.5 grams / 159.69 g/mol

Moles Fe2O3 = 0.147 moles

For 1 mol Fe2O3 we need 3 moles CO to produce 2 moles Fe and 3 moles CO2

For 0.147 moles Fe2O3 we'll have 3*0.147 = 0.441 moles CO2

1 mol = 22.4 L

0.441 moles = 22.4 * 0.441 = <u>9.88 L CO2 </u>

<u />

<u />

<u />

4.How many liters of water vapor would be produced in the combustion of 12.5L of ethane, C2H6 at STP?

2C2H6 + 7O2 →4CO2 + 6H2O

22.4 L = 1 mol

12.5 L = 0.848 moles C2H6

For 2 moles C2H6 we need 7 moles O2 to produce 4 moles CO2 and 6 moles H2O

For 0.848 moles C2H6 we'll have 3*0.848 =  2.544 moles H2O

1 mol = 22.4 L

2.544 moles = 22.4 L * 2.544 = <u>56.99 L H2O</u>

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