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raketka [301]
3 years ago
7

A 25.0 L tank of nitrogen gas is at 25 oC and 2.05 atm . If the temperature stays at 25 oC and the volume is decreased to 14.5 L

, what is the new pressure?
Chemistry
1 answer:
NeTakaya3 years ago
8 0

Answer:

\boxed {\boxed {\sf P_2 \approx 3.53 \ atm}}

Explanation:

In this problem, the temperature stays constant. The volume and pressure change, so we use Boyle's Law. This states that the pressure of a gas is inversely proportional to the volume. The formula is:

P_1V_1=P_2V_2

Now we can substitute any known values into the formula.

Originally, the gas has a volume of 25.0 liters and a pressure of 2.05 atmospheres.

25.0 \ L * 2.05 \ atm = P_2V_2

The volume is decreased to 14.5 liters, but the pressure is unknown.

25.0 \ L * 2.05 \ atm = P_2 * 14.5 \ L

Since we are solving for the new pressure, or P₂, we must isolate the variable. It is being multiplied by 14.5 liters and the inverse of multiplication is division. Divide both sides by 14.5 L .

\frac {25.0 \ L * 2.05 \ atm }{14.5 \ L}=\frac{P_2 *14.5 \ L}{14.5 \ L}

\frac {25.0 \ L * 2.05 \ atm }{14.5 \ L}= P_2

The units of liters cancel.

\frac {25.0  * 2.05 \ atm }{14.5 }=P_2

\frac {50.25\  atm }{14.5 }=P_2

3.53448276 \ atm = P_2

The original values of volume and pressure have 3 significant figures, so our answer must have the same.

For the number we found, that is the hundredth place.

  • 3.53448276

The 4 in the thousandth place (in bold above) tells us to leave the 3 in the hundredth place.

3.53 \ atm \approx P_2

The new pressure is approximately <u>3.53 atmospheres.</u>

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Answer:

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It is possible to calculate the pH of a buffer using H-H equation.

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If concentration of [HCOONa] = [HCOOH] = 0.50M and pH = 3.77:

3.77 = pka + log₁₀ [0.50] / [0.50]

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<em />

Knowing pKa, the NaOH reacts with HCOOH, thus:

HCOOH + NaOH → HCOONa + H₂O

That means the NaOH you add reacts with HCOOH producing more HCOONa.

Initial moles of 100.0mL = 0.1000L:

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After the reaction, moles of each species is:

0.0500moles HCOOH - 0.010 moles NaOH (Moles added of NaOH) = 0.0400 moles HCOOH

0.0500moles HCOONa + 0.010 moles NaOH (Moles added of NaOH) = 0.0600 moles HCOONa

With these moles of the buffer, you can calculate pH:

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<h3>pH = 3.95</h3>

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