Answer: HCl
Explanation:
calcium carbonate dissolves in HCl acid producing CO 2 gas. It will not dissolve in pure water. The Ksp for calcium carbonate in water is 3.4 x 10-9 moldm-3 which is very low. What takes place here is actually a chemical reaction:
CaCO 3 (s) + 2HCl(aq) → CaCl 2 (aq) + H 2CO 3(aq)
This reaction accounts for the solubility of the Calcium carbonate in HCl and not in pure water.
The balanced equation for the above reaction is as follows;
2HCl + K₂SO₃ ---> 2KCl + H₂O + SO₂
stoichiometry of HCl to SO₂ is 2:1
number of moles of HCl reacted - 15.0 g / 36.5 g/mol = 0.411 mol
according to molar ratio
number of SO₂ moles formed - 0.411 mol /2 = 0.206 mol
since we know the number of moles we can find volume using ideal gas law equation
PV = nRT
where
P - pressure - 1.35 atm x 101 325 Pa/atm = 136 789 Pa
V - volume
n - number of moles - 0.206 mol
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - temperature - 325 K
substituting values in the equation
136 789 Pa x V = 0.206 mol x 8.314 Jmol⁻¹K⁻¹ x 325 K
V = 4.07 L
volume of SO₂ formed is 4.07 L
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Answer:
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The answer is C............