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8_murik_8 [283]
3 years ago
11

8) Determine whether mixing each pair of the following results in a buffera. 100.0 mL of 0.10 M NH3 with 100.0 mL of 0.15 MNH4Cl

b. 50.0 mL of 0.10 M HCL with 35.0 mL of 0.150 M NaOHc. 50.0 mL of 0.15 M HF with 20.0 mL of 0.15 M NaOHd. 175.0 mL of 0.10 M NH3 with 150.0 mL of 0.12 M NaOH
Chemistry
1 answer:
Marina86 [1]3 years ago
6 0

Answer:

a. 100.0 mL of 0.10 M NH₃ with 100.0 mL of 0.15 M NH₄Cl.

c. 50.0 mL of 0.15 M HF with 20.0 mL of 0.15 M NaOH.

Explanation:

A buffer system is formed in 1 of 2 ways:

  • A weak acid and its conjugate base.
  • A weak base and its conjugate acid.

Determine whether mixing each pair of the following results in a buffer.

a. 100.0 mL of 0.10 M NH₃ with 100.0 mL of 0.15 M NH₄Cl.

YES. NH₃ is a weak base and NH₄⁺ (from NH₄Cl ) is its conjugate base.

b. 50.0 mL of 0.10 M HCl with 35.0 mL of 0.150 M NaOH.

NO. HCl is a strong acid and NaOH is a strong base.

c. 50.0 mL of 0.15 M HF with 20.0 mL of 0.15 M NaOH.

YES. HF is a weak acid and it reacts with NaOH to form NaF, which contains F⁻ (its conjugate base).

d. 175.0 mL of 0.10 M NH₃ with 150.0 mL of 0.12 M NaOH.

NO. Both are bases.

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Identical wire loops are dipped into Liquid X and Liquid Y, so that a film of liquid forms across the loops (like the bubble sol
muminat

Answer:

a.

Explanation:

Assuming that Liquid X is considered to possess a greater viscosity as well as higher surface tension than liquid Y. Then, liquid X will tend to harbour more pressure inside the liquid.

In addition to that, the greater the surface tension, the greater the force required to expand the liquid's surface area.

This in turn makes the force required to make the loop 5% wider to be greater in FX rather than FY.

Thus, option a is the correct answer.

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3 years ago
What is the pOH of a 0.150 M solution of potassium nitrite? (Ka HNO2 = 4.5 x 10−4 )
yanalaym [24]

Answer:

11.9 is the pOH of a 0.150 M solution of potassium nitrite.

Explanation:

Solution :  Given,

Concentration (c) = 0.150 M

Acid dissociation constant = k_a=4.5\times 10^{-4}

The equilibrium reaction for dissociation of HNO_2 (weak acid) is,

                           HNO_2+H_2O\rightleftharpoons NO_2^-+H_3O^+

initially conc.         c                       0         0

At eqm.              c(1-\alpha)                c\alpha        c\alpha

First we have to calculate the concentration of value of dissociation constant (\alpha ).

Formula used :

k_a=\frac{(c\alpha)(c\alpha)}{c(1-\alpha)}

Now put all the given values in this formula ,we get the value of dissociation constant (\alpha ).

4.5\times 10^{-4}=\frac{(0.150\alpha)(0.150\alpha)}{0.150(1-\alpha)}

4.5\times 10^{-4} - 4.5\times 10^{-4}\alpha =0.150\alpha ^2

0.150\alpha ^2+4.5\times 10^{-4}\alpha-4.5\times 10^{-4}=0

By solving the terms, we get

\alpha=0.0533

No we have to calculate the concentration of hydronium ion or hydrogen ion.

[H^+]=c\alpha=0.150\times 0.0533=0.007995 M

Now we have to calculate the pH.

pH=-\log [H^+]

pH=-\log (0.007995 M)

pH=2.097\approx 2.1

pH + pOH = 14

pOH =14 -2.1 = 11.9

Therefore, the pOH of the solution is 11.9

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