Answer:
Explanation:
We must use the Nernst equation
Step 1. Calculate E°
SO₄²⁻(aq) + 4H⁺(aq) + 2e⁻ ⇌ SO₂(g) + 2H₂O(ℓ)
<u>2Br⁻⇌ Br₂(aq) + 2e⁻ </u>
SO₄²⁻(aq) + 4H⁺(aq) + 2Br⁻(aq) ⇌ Br₂(aq) + SO₂(g) + 2H₂O(ℓ)
E° = 0.17 - 1.0873 = -0.92 V
Step 2. Calculate Q
E = 0 V
E° = -0.92 V
R = 8.314 J·K⁻¹mol⁻¹
T = 66 °C
n = 2
F = 96 485 C/mol
Calculations:
T = 66.0 + 273.15 = 339.15 K
To determine the mass of an atom in terms of atomic mass unit (a.m.u.) the standard should have the fixed mass otherwise the calculated mass of the other atoms will get error. Initially oxygen was used as the reference standard for the calculation of other atoms mass. But after the invention of different isotopes of oxygen i.e. and
which ratios with respect to
is 1.002 the mass of standard oxygen became unstable. Thus the mass of the new atom have error. Thus in 1961 the standard reference is canged to carbon-12. After that onward the mass of the other atoms are measured with respect to carbon.
Answer:
b. cannot exist in optically active form
Explanation:
Stereochemistry is a branch of chemistry that involves the spatial arrangement of the atoms of molecules and studies how this affects the physical and chemical properties of such species.
The correct structure for (2R,3S)‑2,3‑dibromobutane can be seen in the image attached below. Since the compound is a meso compound due to the plane of symmetry. Thus, the compound is achiral. i.e. Compounds that are superimposable on its mirror image. The plane of symmetry is vertical inclined at 90°(i.e. perpendicular) to the page thus goes via the middle of the molecule.
