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AlexFokin [52]
3 years ago
13

ΔU for a van der Waals gas increases by 475 J in an expansion process, and the magnitude of w is 93.0 J.

Chemistry
1 answer:
timofeeve [1]3 years ago
6 0

Complete question:

ΔU for a van der Waals gas increases by 475 J in an expansion process, and the magnitude of w is 93.0 J. calculate the magnitude of q for the process.

Answer:

The magnitude of q for the process 568 J.

Explanation:

Given;

change in internal energy of the gas, ΔU = 475 J

work done by the gas, w = 93 J

heat added to the system, = q

During gas expansion process, heat is added to the gas.

Apply the first law of thermodynamic to determine the magnitude of heat added to the gas.

ΔU = q - w

q = ΔU +  w

q = 475 J  +  93 J

q = 568 J

Therefore, the magnitude of q for the process 568 J.

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<u>Answer:</u> The correct answer is NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]

<u>Explanation:</u>

Molecularity of the reaction is defined as the number of atoms, ions or molecules that must colloid with one another simultaneously so as to result into a chemical reaction.

Order of the reaction is defined as the sum of the concentration of terms on which the rate of the reaction actually depends. It is the sum of the exponents of the molar concentration in the rate law expression.

Elementary reactions are defined as the reactions for which the order of the reaction is same as its molecularity and order with respect to each reactant is equal to its stoichiometric coefficient as represented in the balanced chemical reaction.

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  • <u>Equation 2:</u>  H_2(g)+Br_2(g)\rightarrow 2HBr(g);Rate=k[H_2][Br_2]^{1/2}

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  • <u>Equation 3:</u>  NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]

Molecularity of the reaction = 1 + 1 = 2

Order of the reaction = 1 + 1 = 2

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  • <u>Equation 4:</u>  NO_2(g)+CO(g)\rightarrow NO(g)+CO_2(g);Rate=k[NO_2]^2

Molecularity of the reaction = 1 + 1 = 2

Order of the reaction = 2 + 0 = 2

In this equation, the order with respect to each reactant is not equal to its stoichiometric coefficient which is represented in the balanced chemical reaction. Hence, this is not considered as an elementary reaction.

Hence, the correct answer is NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]

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