Predict the number of peaks that you would expect in the proton-decoupled 13C spectrum of each comound.
1 answer:
Answer:
To interpret a 13C-NMR spectrum we will use some standards very simple. A 13C-NMR spectrum gives us the following information:
1. Indicates the number of non-equivalent carbons in the molecule.
2. Measuring the chemical shift we can intuit the environment
electronic and determine the next functional groups.
3. In this case we cannot count on integration since the different
carbons have different relaxation times.
The number of peaks in the spectrum indicates the number of types of carbon present in the analyzed substance.
The factors that influence the chemical shift of the signals in the 13C NMR are:
- electronegativity of carbon bound groups
- carbon hybridization
Explanation:
The nuclear magnetic resonance of C13 is complementary to that of H1. This technique is used to determine the magnetic environment of carbon atoms.
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Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong