Predict the number of peaks that you would expect in the proton-decoupled 13C spectrum of each comound.
1 answer:
Answer:
To interpret a 13C-NMR spectrum we will use some standards very simple. A 13C-NMR spectrum gives us the following information:
1. Indicates the number of non-equivalent carbons in the molecule.
2. Measuring the chemical shift we can intuit the environment
electronic and determine the next functional groups.
3. In this case we cannot count on integration since the different
carbons have different relaxation times.
The number of peaks in the spectrum indicates the number of types of carbon present in the analyzed substance.
The factors that influence the chemical shift of the signals in the 13C NMR are:
- electronegativity of carbon bound groups
- carbon hybridization
Explanation:
The nuclear magnetic resonance of C13 is complementary to that of H1. This technique is used to determine the magnetic environment of carbon atoms.
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a) Catalysts are the substance which alter the reaction pathway where activation energy of reaction is less that the un catalyzed reaction. They are not used up in the reaction . the catalyst is restored in the reaction.
b) As mentioned above, the catalyst speed up reaction by lowering the activation energy
c) During a reaction the reactants are consumed up and products are formed. so there is a decrease in concentration of reactant.
Thus all the above statements are true.
D) the rate of decrease in concentration of reactants depends upon the coefficient of reactant in balanced chemical reaction.
For example
Here the rate of decrease in concentration of hydrogen will be double the rate of decrease in concentration of oxygen.