Predict the number of peaks that you would expect in the proton-decoupled 13C spectrum of each comound.
1 answer:
Answer:
To interpret a 13C-NMR spectrum we will use some standards very simple. A 13C-NMR spectrum gives us the following information:
1. Indicates the number of non-equivalent carbons in the molecule.
2. Measuring the chemical shift we can intuit the environment
electronic and determine the next functional groups.
3. In this case we cannot count on integration since the different
carbons have different relaxation times.
The number of peaks in the spectrum indicates the number of types of carbon present in the analyzed substance.
The factors that influence the chemical shift of the signals in the 13C NMR are:
- electronegativity of carbon bound groups
- carbon hybridization
Explanation:
The nuclear magnetic resonance of C13 is complementary to that of H1. This technique is used to determine the magnetic environment of carbon atoms.
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Answer:
Kc = 0.075
Explanation:
The dissociation (α) is the initial quantity that ionized divided by the total dissolved. So, let's calling x the ionized quantity, and M the initial one:
α = x/M
x = M*α
x = 0.354M
For the stoichiometry of the reaction (2:1:1), the concentration of H₂ and I₂ must be half of the acid. So the equilibrium table must be:
2HI(g) ⇄ H₂(g) + I₂(g)
M 0 0 <em> Initial</em>
-0.354M +0.177M +0.177M <em>Reacts</em>
0.646M 0.177M 0.177M <em>Equilibrium</em>
The equilibrium constant Kc is the multiplication of the products' concentrations (elevated by their coefficients) divided by the multiplication of the reactants' concentrations (elevated by their coefficients):
Kc = 0.075