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Sladkaya [172]
2 years ago
15

Consider the following isomerization reactions of some simple sugars and values for their standard Gibbs free energy ΔGo:reactio

n A: glucose-1-phosphate rightarrow glucose-6-phosphate, ΔGo = -7.28 kJ/mol reaction B: fructose-6-phosphate rightarrow glucose-6-phosphate, ΔGo = -1.67 kJ/molCalculate for the isomerization of glucose-1-phosphate to fructose-6-phosphate.Calculate the equilibrium constant K for the isomerization of glucose-1-phosphate to fructose-6-phosphate at 298 K.
Chemistry
1 answer:
koban [17]2 years ago
3 0

Answer:

Explanation:

glucose-1-phosphate  →  glucose-6-phosphate,  ΔGo = -7.28 kJ/mol

fructose-6-phosphate → glucose-6-phosphate,    ΔGo = -1.67 kJ/mol

subtracting the equation

glucose-1-phosphate - fructose-6-phosphate  = 0 , ΔGo =  -7.28  - ( -1.67 ) kJ / mol

glucose-1-phosphate  = fructose-6-phosphate      ΔGo  = - 5.61 kJ / mol

- ΔGo = RT lnK

5.61 x 10³ = 8.31 x 298 x lnK

lnK = 2.265

K = 9.63 .

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If 500ml of H₂ gas at 600mmHg and 400ml of CO₂ gas at 700mmHg are mixed in a 1 lit vessel, find the total pressure of mixture of
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Answer:

Total pressure increased

Explanation:

When gas C is added in the vessel then number of mole increases and number of collision depends on the number of molecules present in the vessel and on adding gas C ,mole also increases hence  number of collision increases therefore pressure also increases because number of collision increases.

Total pressure increases.

6 0
2 years ago
What happens to the temperature and density of the material between points B and C?
makvit [3.9K]

Answer:

Temperature decreases and density increases

Explanation:

Let us remember that density of a material increases as the temperature of the material decreases. So the cooler a material becomes, the denser it becomes also.

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7 0
3 years ago
Sulfonation of benzene has the following mechanism: (1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3 [fast] (2) SO3 + C6H6 → H(C6H5+)SO3− [slow]
ziro4ka [17]

Question is incomplete, complete question is as follows :

Complete Question : .Sulfonation of benzene has the following mechanism:

(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3

[fast]

(2) SO3 + C6H6 → H(C6H5+)SO3−

[slow]

(3) H(C6H5+)SO3− + HSO4− → C6H5SO3− + H2SO4

[fast]

(4) C6H5SO3− + H3O+ → C6H5SO3H + H2O

[fast]

write the overall rate law for the initial rate of the reaction as a fraction.

Rate=k(________/_________)

Answer:

The overall rate law for the initial reaction is = k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]

Explanation :

Frist of all, all the common terms are cancelled out and written the overall reaction.

As we know that the rate depednant step is the slowest step of the reaction, rate law is :

                        rate = k_{2} [SO_{3}][C_{6}H_{6}]

But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.

Rate law for synthesis of S03 is as follows :

                       rate = k_{1}[H_{2}SO_{4}]^{2}

Hence when we substitute equation 2 in equation one,

                   Rate comes out to be =  k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]

6 0
2 years ago
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