Answer:
Only
gives spontaneous reaction.
Explanation:
A redox reaction will be spontaneous if standard reduction potential (
) of the reaction is positive. Because it leads to negative standard gibbs free energy change (
), which is a thermodynamic condition for spontaneity of a reaction.

Where
and
represents standard reduction potential of reduction half cell and standard reduction potential of oxidation half cell.
(1) Oxidation:
; 
Reduction:
; 
So, 
Hence this pair will give spontaneous reaction.
(2) Similarly as above, 
Hence this pair will give non-spontaneous reaction.
(3) Similarly as above, 
Hence this pair will give non-spontaneous reaction.
(4) Similarly as above, 
Hence this pair will give non-spontaneous reaction.
The answer should be <span>balance electrically
</span><span>Chemical reactions that form ions should have a balanced charge. The example of the reaction is HCl. When forming ions, the equation should be:
HCl => </span>

+

In this case, the hydrogen has one plus charge and chlorine has one negative charge. The resultant should be zero, so it's balanced.
Answer:
6.68 X 10^-11
Explanation:
From the second Ka, you can calculate pKa = -log (Ka2) = 6.187
The pH at the second equivalence point (8.181) will be the average of pKa2 and pKa3. So,
8.181 = (6.187 + pKa3) / 2
Solving gives pKa3 = 10.175, and Ka3 = 10^-pKa3 = 6.68 X 10^-11