Answer:
I think it was Hillary Clinton.
Explanation:
Answer: 289.1 torr ..........
Answer : The cell potential for this reaction is 0.50 V
Explanation :
The given cell reactions is:

The half-cell reactions are:
Oxidation half reaction (anode): 
Reduction half reaction (cathode): 
First we have to calculate the cell potential for this reaction.
Using Nernest equation :
![E_{cell}=E^o_{cell}-\frac{2.303RT}{nF}\log \frac{[Zn^{2+}]}{[Pb^{2+}]}](https://tex.z-dn.net/?f=E_%7Bcell%7D%3DE%5Eo_%7Bcell%7D-%5Cfrac%7B2.303RT%7D%7BnF%7D%5Clog%20%5Cfrac%7B%5BZn%5E%7B2%2B%7D%5D%7D%7B%5BPb%5E%7B2%2B%7D%5D%7D)
where,
F = Faraday constant = 96500 C
R = gas constant = 8.314 J/mol.K
T = room temperature = 
n = number of electrons in oxidation-reduction reaction = 2
= standard electrode potential of the cell = +0.63 V
= cell potential for the reaction = ?
= 3.5 M
= 
Now put all the given values in the above equation, we get:


Therefore, the cell potential for this reaction is 0.50 V
The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴ ![8.3 = 8.3 + log \frac{[0.005]}{[0.005]}](https://tex.z-dn.net/?f=8.3%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005%5D%7D%7B%5B0.005%5D%7D)
<em> </em>inverse log 0 = ![\frac{[B]}{[A]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D)
![\frac{[B]}{[A]} = 1](https://tex.z-dn.net/?f=%5Cfrac%7B%5BB%5D%7D%7B%5BA%5D%7D%20%3D%201)
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
![pH = 8.3 + log \frac{[0.005-0.003]}{[0.005+0.003]}\\pH = 8.3 + log \frac{[0.002]}{[0.008]}\\\\pH = 8.3 + log {0.25}\\\\pH = 8.3 + (-0.62)\\pH = 7.69](https://tex.z-dn.net/?f=pH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.005-0.003%5D%7D%7B%5B0.005%2B0.003%5D%7D%5C%5CpH%20%3D%208.3%20%2B%20log%20%5Cfrac%7B%5B0.002%5D%7D%7B%5B0.008%5D%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20log%20%7B0.25%7D%5C%5C%5C%5CpH%20%3D%208.3%20%2B%20%28-0.62%29%5C%5CpH%20%3D%207.69)
Therefore, the new pH is 7.69.
Learn more about pH here:
brainly.com/question/24595796
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