Alkenes on reacting with ozone results in the formation of ozonide which undergo reductive cleavage in presence of dimethyl sulfide to form carbonyl compounds (aldehyde or ketone). Whereas in presence of hydrogen peroxide it undergoes oxidative cleavage to form carboxylic acids or ketones.
Since, A alkene yields 4-heptanone only on treatment with ozone and DMS thus, it implies that both the chains on the side of the double-bond are similar the product is 4-heptanone that means the double bond is present between the chains at the 4th carbon. Therefore the structure of compound A is 4,5-dipropyloct-4-ene.
The reaction is as shown in the image.
The reaction of A with m-CPBA (meta-perchlorobenzoic acid) followed by aqueous acid
is shown in the image.
m-CPBA (meta-perchlorobenzoic acid) is a peracid and forms epoxides on reacting with alkenes.
Answer:
The pH is 7.54
Explanation:
The Henderson - Hasselbalch equation states that for a buffer solution which consists of a weak acid and its conjugate base, the buffer pH is given by:
pH ![=pk_{a} +log(\frac{[conjugate base]}{[weakacid]})](https://tex.z-dn.net/?f=%3Dpk_%7Ba%7D%20%2Blog%28%5Cfrac%7B%5Bconjugate%20base%5D%7D%7B%5Bweakacid%5D%7D%29)
pkₐ is for the acid
In this case, the buffer hypochlorous acid HClO is a weak acid, and its conjugate base is the hypochlorite anion ClO⁻ is delivered to the solution via sodium hypochlorite NaClO
.
NaCIO = 0.200 M
HCIO = 0.200 M
pkₐ = -log₁₀ kₐ = -log₁₀ (2.9 × 10⁻⁸) = 7.54
∴pH =
= 7.54
The required volume of water to make the dilute solution of 0.5 M is 188 mL.
<h3>How do we calculate the required volume?</h3>
Required volume of water to dilute the stock solution will be calculated by using the below equation as:
M₁V₁ = M₂V₂, where
- M₁ & V₁ are the molarity and volume of stock solution.
- M₂ & V₂ are the molarity and volume of dilute solution.
On putting values from the question to the above equation, we get
V₂ = (2)(47) / (0.5) = 188mL
Hence required volume of water is 188 mL.
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In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s² 2s² 2p⁶, using the notation explained below
Explanation:
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