Answer:
1) Endothermic.
2)
3)
Explanation:
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1) In this case, for these calorimetry problems, we can realize that since the temperature decreases the reaction is endothermic because it is absorbing heat from the solution, that is why the temperature goes from 22.00 °C to 16.0°C.
2) Now, for the total heat released by the reaction, we first need to assume that all of it is released by the solution since it is possible to assume that the calorimeter is perfectly isolated. In such a way, it is also valid to assume that the specific heat of the solution is 4.184 J/(g°C) as it is mostly water, therefore, the heat released by the reaction is:
3) Finally, since the enthalpy of reaction is calculated by dividing the heat released by the reaction over the moles of the solute, in this case NH4Cl, we proceed as follows:

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I’d say A. They are theoretical in the fact that they have not been observed directly, but have been confirmed to exist through experimentation.
The mass of 254 mL of water is 254 g. Since the density of water is 1g/mL, we can simply multiply the density 1g/mL by 254 mL of water and get 254 g as our answer. Since mL is in the numerator and denominator, mL cancels out and we are left with g only.
All copper atoms have atomic number 29: all their nuclei contain 29 protons. But they also contain uncharged particles called neutrons. ... The two different kinds of atom are called isotopes of copper. The neutron has a mass very similar to that of the proton, so the two isotopes differ in mass.