Answer:
a. A reaction in which the entropy of the system increases can be spontaneous only if it is endothermic.
Explanation:
The change in free energy (ΔG) that is, the <u>energy available to do work</u>, of a system for a constant-temperature process is:

-
When ΔG < 0 the reaction is spontaneous in the forward direction.
- When ΔG > 0 the reaction is nonspontaneous. The reaction is
spontaneous in the opposite direction.
- When ΔG = 0 the system is at equilibrium.
If <u>both ΔH and ΔS are positive</u>, then ΔG will be negative only when the TΔS term is greater in magnitude than ΔH. This condition is met when T is large.
Answer:
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Explanation:
Answer:

Explanation:
Hello,
In this case, it is widely known that for isochoric processes, the change in the enthalpy is computed by:

Whereas the change in the internal energy is computed by:
So we compute the initial and final temperatures for one mole of the ideal gas:

Next, the change in the internal energy, since the volume-constant specific heat could be assumed as ³/₂R:

Then, the volume-pressure product in Joules:

Finally, the change in the enthalpy for the process:

Best regards.