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2 answers:
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Explanation:
Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:
The mixture would contain
of
and
of
if undergoes no hydrolysis; the solution is of volume
after the mixing. The two species would thus be of concentration
and
, respectively.
Construct a RICE table for the hydrolysis of under a basic aqueous environment (with a negligible hydronium concentration.)
The question supplied the <em>acid</em> dissociation constant for acetic acid
; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant
for its conjugate base,
. The following relationship relates the two quantities:
... where the water self-ionization constant under standard conditions. Thus
. By the definition of
:
Answer : The balanced chemical equation is,
Explanation :
Rules for the balanced chemical equation in basic solution are :
- First we have to write into the two half-reactions.
- Now balance the main atoms in the reaction.
- Now balance the hydrogen and oxygen atoms on both the sides of the reaction.
- If the oxygen atoms are not balanced on both the sides then adding water molecules at that side where the more number of oxygen are present.
- If the hydrogen atoms are not balanced on both the sides then adding hydroxide ion
at that side where the less number of hydrogen are present.
- Now balance the charge.
The half reactions in the basic solution are :
Reduction : ......(1)
Oxidation : .......(2)
Now multiply the equation (1) by 2 and then added both equation, we get the balanced redox reaction.
The balanced chemical equation in a basic solution will be,