(C) A metal 'M' has electronic configuration 2, 8, 2. Find the formula of its
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Given :
Number of atoms of an element, n = 2.072 × 10⁴³ atoms.
To Find :
Number of moles of that element in given number of atoms.
Solution :
We know, 1 mole of any element contains 6.022 × 10²³ atoms.
So, number of moles in given number of atoms are :
Hence, this is the required solution.
Structure along with ¹H-NMR is shown below.
Signal for Hₐ;
Based on multiplicity of of the peak, a Singlet peak (the only singlet peak present in spectrum) at 2.2 ppm was assigned to Hₐ. As the methyl group in not coupling with any other proton so it gave a singlet peak.
Signal for Hb;
Based on multiplicity of of the peak, a Quartet peak (the only quartet peak present in spectrum) at 2.4 ppm was assigned to Hb. As the methylene group in coupling with methyl group having three protons so it gave a Quartet peak.
Signal for Hc;
Based on multiplicity of of the peak, a Triplet peak (the only triplet peak present in spectrum) at 1.1 ppm was assigned to Hc. As the methyle group in coupling with methylene group having two protons so it gave a Triplet peak.
Signal for Hₐ;
Based on multiplicity of of the peak, a Singlet peak (the only singlet peak present in spectrum) at 2.2 ppm was assigned to Hₐ. As the methyl group in not coupling with any other proton so it gave a singlet peak.
Signal for Hb;
Based on multiplicity of of the peak, a Quartet peak (the only quartet peak present in spectrum) at 2.4 ppm was assigned to Hb. As the methylene group in coupling with methyl group having three protons so it gave a Quartet peak.
Signal for Hc;
Based on multiplicity of of the peak, a Triplet peak (the only triplet peak present in spectrum) at 1.1 ppm was assigned to Hc. As the methyle group in coupling with methylene group having two protons so it gave a Triplet peak.
The new pH is 7.69.
According to Hendersen Hasselbach equation;
The Henderson Hasselbalch equation is an approximate equation that shows the relationship between the pH or pOH of a solution and the pKa or pKb and the ratio of the concentrations of the dissociated chemical species. To calculate the pH of the buffer solution made by mixing salt and weak acid/base. It is used to calculate the pKa value. Prepare buffer solution of needed pH.
pH = pKa + log10 ([A–]/[HA])
Here, 100 mL of 0.10 m TRIS buffer pH 8.3
pka = 8.3
0.005 mol of TRIS.
∴
<em> </em>inverse log 0 =
Given; 3.0 ml of 1.0 m hcl.
pka = 8.3
0.003 mol of HCL.
Therefore, the new pH is 7.69.
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