Answer:
B. Cu + 4HNO3 → Cu(NO3)2 + 2H2O + 2NO2
Explanation:
Hello,
In this case, we should understand oxidizing agents as those substances able to increase the oxidation state of another substance, therefore, in B. reaction we notice that copper oxidation state at the beginning is zero (no bonds are formed) and once it reacts with nitric acid, its oxidation states raises to +2 in copper (II) nitrate, thus, in B. Cu + 4HNO3 → Cu(NO3)2 + 2H2O + 2NO2 nitritc acid is acting as the oxidizing agent.
Moreover, in the other reactions, copper (A.), sodium (C. and D.) remain with the same initial oxidation state, +2 and +1 respectively.
Regards.
<span>Igneous rock that cools very quickly when it forms may have a texture that is smooth and shiny with no visible grain.</span>
Answer:
Elements and compounds are two types of pure substances.
Explanation:
Here we have to draw the mechanism of the reduction reaction between benzaldehyde and sodium borodeuteride to form the corresponding alcohol.
The reducing agent sodium borodeuteride can reduce the aldehydes to its corresponding alcohol. The reaction mechanism is shown in the attached image.
The reaction mechanism can be explained as-
The sodium borodeuteride is highly ionic in nature thus it remains as Na⁺ and BD₄⁻ The deuterium atom of BD₄⁻ attack the carbonyl carbon atom and substitute one of its deuterium as shown in the figure.
One molecule of sodium borodeuteride can reduce four molecules of benzaldehyde. The polar solvent like alcohol donates the proton as shown in the mechanism.
The converted alcohol contains the deuterium atom at the -C center. Thus benzaldehyde is converted to deuteroted benzyl alcohol.
Answer:
A Fridiel craft catalyst will convert benzene to acetophenone.
Permanganate catalyst can be used to convert toluene to acetophenone.
Explanation:
Benzene can be reduced to acetophenone by the addition of anhydrous aluminium chloride, AlCl₃
The mechanism is as follows:
Benzene + Acetyl choloride → acetophenone
To convert toluene to acetophenone, the following steps are necessary:
- Oxidation of Toluene to Benzoic acid.
This is done by refluxing toluene with alkaline potassium permanganate (KMnO₄+ Na₂CO₃).
-
Benzoic acid is converted to Benzoyl chloride by treating with thioyl chloride and heating at about 80 ⁰C.
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Benzoyl chloride is treated with methyl lithium to form Acetophenone.
