The overall reaction is given by:

The fast step reaction is given as:

The slow step reaction is given as:
(slow step
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as
takes place in this reaction.
The expression of rate of formation is:

=
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of
in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of
in terms of reactants is given by
.
Answer:
The values for spin quantum number +1/2 and - 1/2
Explanation:
Principal quantum number denoted by (n) is used to describe the shell or orbits that electrons are found. Principal quantum number can assume a value of n= 1,2, 3, 4,5............ which indicates K, L, M, N, O shell respectively.
To know the maximum number of electrons in each shell, the formula (2n²) can be used. The letter 'n' denotes the values of principal quantum number 1,2,3,4
For example
- n=1 (K shell) has maximum number of 2 electrons
- n=2 (L shell) has the maximum number of 8 electrons
- n=3 (M shell) has the maximum number of 18 electrons
- n=4 (N shell) has the maximum number of 32 electrons
All the electron in each shell will have a spin quantum number of +1/2 and - 1/2. One electron in each degenerate orbital will spin up (+1/2) while the other electron will spin down (-1/2).
The answer is Metalloids!
Answer:
The true statements are:
The solution is acidic
The pH of the solution is 14.00 - 10.53.
![10^{-10.53}=[OH^-]](https://tex.z-dn.net/?f=10%5E%7B-10.53%7D%3D%5BOH%5E-%5D)
Explanation:
The pH of the solution is defined as negative logarithm of hydrogen ion concentration present in the solution .
![pH=-\log[H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5BH%5E%2B%5D)
- The pH value more 7 means that hydrogen ion concentration is less ,alkaline will be the solution.
- The pH value less 7 means that hydrogen ion concentration is more ,acidic will be the solution.
- The pH value equal to 7 indicates that the solution is neutral.
The pOH of the solution is defined as negative logarithm of hydroxide ion concentration present in the solution .
![pOH=-\log[OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%5BOH%5E-%5D)
The pOH of the solution = 10.53
![10.53=-\log[OH^-]](https://tex.z-dn.net/?f=10.53%3D-%5Clog%5BOH%5E-%5D)
![10^{-10.53}=[OH^-]](https://tex.z-dn.net/?f=10%5E%7B-10.53%7D%3D%5BOH%5E-%5D)
The pH of the solution = ?


Here, the pH of the solution is less than 7 which means that solution acidic.