According to the kinetic molecular theory, the particles of an ideal gas
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Answer:
a) If the reaction has a large negative ΔGo value, the reaction must reach equilibrium at a small extent of reaction value
d) ΔGo and ΔG have the same magnitude, they just have opposite signs.
Explanation:
The fraction of the total heat energy if a system that does useful work is known as Gibb's free energy (G) and the change from the initial to final state is designated by . It is observed that the values of
changes with experimental conditions such as temperature , pressure , concentration etc.
is the standard free energy change which is a balance of two natural tendencies of any system.
- Minimization of potential energy or enthalpic factor
Maximization of disorderliness or entropic factor
Mathematically; =
-
Thus; from above mentioned, the statements that are true about ΔG⁰ and ΔG are:
ΔG⁰ and ΔG can have different values, they don't even have to have the same sign
For a reaction that reaches equilibrium, the minimum value of free energy must be at the equilibrium point
If ΔG⁰ , measured at an extent of reaction = 0.5, is positive, the sign for ΔG when the extent of reaction = 0.80 is also positive.
while the false statements include:
a) If the reaction has a large negative ΔG⁰ value, the reaction must reach equilibrium at a small extent of reaction value
d) ΔG⁰ and ΔG have the same magnitude, they just have opposite signs.
Answer : The change in internal energy is, 900 Joules.
Solution : Given,
Heat given to the system = +1400 J
Work done by the system = -500 J
Change in internal energy is equal to the sum of heat energy and work done.
Formula used :
where,
= change in internal energy
q = heat energy
w = work done
As per question, heat is added to the system that means, q is positive and work done by the system that means, w is negative.
Now put all the given values in the above formula, we get
Therefore, the change in internal energy is 900 J.
The change in internal energy depends on the heat energy and work done. As we will change in the heat energy and work done, then changes will occur in the internal energy. Hence, the energy is conserved.