Answer:
- The molar mass of the solute, in order to convert from moles of solute to grams of solute.
- The density of solution, to convert from volume of solution to mass of solution.
Explanation:
Hello,
In this case, since molarity is mathematically defined as the moles of solute divided by the volume of solution and the weight/weight percent as the mass of solute divided by the mass of solution, we need:
- The molar mass of the solute, in order to convert from moles of solute to grams of solute.
- The density of solution, to convert from volume of solution to mass of solution.
For instance, if a 1-M solution of HCl has a density of 1.125 g/mL, we can compute the w/w% as follows:

Whereas the first factor corresponds to the molar mass of HCl, the second one the conversion from L to mL of solution and the third one the density to express in terms of grams of solution.
Regards.
Answer:
![[Ag^{+}]=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
Explanation:
Given:
[AgNO3] = 0.20 M
Ba(NO3)2 = 0.20 M
[K2CrO4] = 0.10 M
Ksp of Ag2CrO4 = 1.1 x 10^-12
Ksp of BaCrO4 = 1.1 x 10^-10

![Ksp=[Ba^{2+}][CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BBa%5E%7B2%2B%7D%5D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.2\times 10^{-10}=(0.20)[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-10%7D%3D%280.20%29%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}](https://tex.z-dn.net/?f=%5BCrO_%7B4%7D%5E%7B2-%7D%5D%3D%5Cfrac%7B1.2%5Ctimes%2010%5E%7B-10%7D%7D%7B%280.20%29%7D%3D%206.0%5Ctimes%2010%5E%7B-10%7D)
Now,

![Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})](https://tex.z-dn.net/?f=1.1%5Ctimes%2010%5E%7B-12%7D%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%286.0%5Ctimes%2010%5E%7B-10%7D%29)
![[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%3D%5Cfrac%7B1.1%5Ctimes%2010%5E%7B-12%7D%7D%7B%286.0%5Ctimes%2010%5E%7B-10%7D%29%7D%3D%201.8%5Ctimes%2010%5E%7B-3%7D)
![[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D%5Csqrt%7B1.8%5Ctimes%2010%5E%7B-3%7D%7D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M
Answer:
28.7664 kJ /mol
Explanation:
The expression for Clausius-Clapeyron Equation is shown below as:

Where,
P is the vapor pressure
ΔHvap is the Enthalpy of Vaporization
R is the gas constant (8.314×10⁻³ kJ /mol K)
c is the constant.
The graph of ln P and 1/T gives a slope of - ΔHvap/ R and intercept of c.
Given :
Slope = -3.46×10³ K
So,
- ΔHvap/ R = -3.46×10³ K
<u>ΔHvap = 3.46×10³ K × 8.314×10⁻³ kJ /mol K = 28.7664 kJ /mol</u>
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